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静电纺丝中几组不同配比的PCL/PLA的性能比较 被引量:1

The Performance Comparison between PCL and PLA under the Condition of Several Various Proportion in Electrostatic Spinning
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摘要 采用静电纺丝技术来纺制不同配比的PCL/PLA纳米纤维,研究了电压及PCL/PLA组分的比例等参数对纤维表面形貌及拉伸强度的影响,采用扫描电镜来观察纤维的直径及其形态。用万能试验机测量材料的拉伸强度,发现随着PLA比例的减少,材料可承受的最大应力降低。最后参数优化选择电压为24 kV,PCL/PLA的配比为5:5时可纺出综合性能较优越的纤维。 The article is mainly about the way in making nanofiber of PCL/PLA under the condition of various proportion with the technique of electrostatic spinning. It studies the affection from voltage as well as various proportion of PCL/PLA on both the surface morphology and the tensile strength of the fiber whose diameter and form will be observed with the help of scanning electron microscope.Universal testing machine will be used to measure the tensile strength of the material. However, with the decrease of the PLA proportion, the maximum principal stress which the material can support will decrease as well. Therefore, while theparameter optimization of the voltage is 24 kV, the proportion of PCL/PLA is 5 : 5, then the superior fber with comprehensive qualities will be produced.
出处 《广东化工》 CAS 2013年第11期16-17,44,共3页 Guangdong Chemical Industry
关键词 静电纺丝 表面形貌 最大应力 参数优化 electrostatic spinning surface morphology maximum principal stress parameter optimization
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参考文献17

  • 1FormhalsA. USP, I 975504. 1934.
  • 2D Li, Y N Xia. Electrospinning of nanofibers: Reinventing the wheel[J]. Advanced Materials, 2004, 16: 1151-1170.
  • 3仰大勇,蒋兴宇.静电纺丝制备有序纳米纤维的研究进展[J].合成纤维,2008,37(6):1-5. 被引量:18
  • 4A Greiner, J H Wendorff. Electrospinning: A fascinating method for the preparation ofultrathin fibres[J]. Angewandte Chemie-lnternational Edition,2007, 46: 5670-5703.
  • 5L Jiang, Y Zhao, J Zhai. A lotus-leaf-like superhydrophobic surface: A porous microsphere/nanofiber composite film prepared by electrohydrodynamics[J]. Angewandte Chemie-lntemational Edition, 2004, 43: 4338-4341.
  • 6J F Zheng, A H He, et al. Studies on the controlled morphology and wettability of polystyrene surfaces by electrospinning or electrospraying[J]. Polymer, 2006, 47: 7095-7102.
  • 7Y F Yao, Z Z Gu, et al. Fiber-oriented liquid crystal polarizers based on anisotropicelectrospinning[J]. Advanced Materials, 2007, 19: 3707-3711.
  • 8J H He. Electrospinning: The big world of small fibers[J]. Polymer International, 2007, 56: 1321-1322.
  • 9Y Zhao, X Y Cao, L Jiang. Bio-mimic multichannel microtubes by a facile method[J]. Journal ofthe American Chemical Society, 2007, 129: 764-765.
  • 10J F Zheng, A H He, J Li, C CHan. Polymorphism control of poly(vinylidene fluoride)through electrospinning[J]. Macromolecular Rapid Communications, 2007, 28: 2159-2162.

二级参考文献56

  • 1廷璋.静电纺丝纳米纤维的新进展和未来动向[J].高科技纤维与应用,2011,36(1):32-35. 被引量:4
  • 2Nicole Rutherford,彭增辉.有机显示器和电子器件的柔性基板和封装[J].现代显示,2006(1):24-29. 被引量:5
  • 3渡边幸二.对细度的挑战:海岛纺丝(聚酯)[J].纤维学会志,1998,54(4):19-23.
  • 4Xie Jingwei,Liu Wenying,Matthew R MacEwan.Tissueengineering:nanofiber membranes with controllable mi-crowells and structural cues and their use in forming cellmicroarrays and neuronal networks[J].Small,2011,7(3):285-290.
  • 5陈慧文 容敏智.催化挤出聚合纳米纤维应用.材料导报,2002,:58-59.
  • 6Avinash P.Manian,Hartmut Ruef,Thomas Bechtold.Spun-dyed lyocell[J].Dyes and Pigments,2007,74(3):519-524.
  • 7Zhang Hai-tao,Li Shu-bai,Christopher J,et al.Studies onelectrospun nylon-6/chitosan complex nanofiber interac-tions[J].Electrochimica Acta,2009,54(24):5739-5745.
  • 8Yarin A L,Koombhongse S,Reneker D H.Taylor coneand jetting from liquid droplets in electrospinning of nanofi-bers[J].Journal of AppliedPhysics,2001,90(8):36-46.
  • 9Reneker D H,Chun I.Nanometer diameter fibers of poly-mer produced by electrospinning[J].Nanotechnology1996,7(2):16-23.
  • 10Ziabicki A.Fundamentals of Fibre Formation:the scienceof fibre spinning and drawing[M].New York:Wiley.1976.

共引文献21

同被引文献9

  • 1任杰,杨军,任天斌.生物可降解材料聚乳酸结晶行为研究进展[J].高分子通报,2006(12):51-56. 被引量:32
  • 2周林.PLLA和PCL纳米复合材料熔体流动行为及其机理研究[D].广州:华南理工大学,2012.
  • 3Isabelle V,LanT.Biodegradable polymers[J].Materials,2009,2:307-344.
  • 4Hu W B.The principle of macromolecular crystallography[M].[S.l.]:Kluwer Academic Publishers.2013.
  • 5Schwach G,Coudane J,Engel R.Ring opening polymerization of D1 L-lactidc in the presence of zinc metal and zinc lactate[J].Polym.Int.,1998,46:177-187.
  • 6Bigi A,Boanini E,Maglio G,et al.PLLA based composites with a- tricalcium phosphate and a PLLA-PEO diblock copolymer[J].Macromol.Symposia,2006,234:26-32.
  • 7Ross S,Mahasaranon S,Ross G M.Ternary polymer blends based on.poly (lactic acid):effect of stereo-regularity and molecular weight[J].J.Appl.Polym-Sci.,2014,132:DOl:10.1002/ app.41780.
  • 8Buddhiranon S,Kim N,Kyu T.Morphology developmenl in relation to the ternary phase diagram of biodegradable PDLLA/PCL/PEC) blends[J].Macromol.Chem.Phys.,2011,212:1379-1391.
  • 9陈咏,窦强.成核剂对聚乳酸结晶及力学性能的影响[J].现代塑料加工应用,2012,24(6):39-42. 被引量:10

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