摘要
利用微分脉冲伏安法研究了对称四甲基六元瓜环(TMeQ[6])与过渡金属的相互作用。结果表明该主体大环化合物对Pb2+和Cd2+离子具有较好的选择性作用。伏安数据测定表明Pb2+及Cd2+离子与对称四甲基六元瓜环以nM2+/nTMeQ[6]=2配位,其配合平衡常数分别为(KPb2+=2.12×109L2·mol-2,KCa2+=2.10×109L2·mol-2)。Pb2+离子与TMeQ[6]的晶体结构进一步证实了上述实验结果。
The complexation of α,α'δ,δ'-tetramethylcucurbit[6]nril (TMeQ[6]) complexes with transition-metal ions was studied by differential pulse vohammetry (DPV). The results reveal that this water-soluble cage-type compound shows very high selectivity for Pb^2+ and Cd^2+, while it is a masking compound for other transition-metal ions, particularly for Fe^3+, Co^2+, Zn^2+, and Cr3+, due to a sharp decrease in the DPV peak current of these metal ions in the presence of TMeQ[6]. Binding constants were determined from vohammetric data. The Pb2+ and Cd2+ cations display a high binding affinity for TMeQ[6] (Kpb2+=2.12×10^9 L2·mo1-2, Kca2+=2.10×10^9 L2·mo1-2) and form 2:1 nM2+/nTMeQ[6] complexes. The crystal structure of TMeQ[6]-Pb^2+ indicates a 2:1 (nPb2+/nTMeQ[6]) complex in the solid state, which is consistent with the results in solution. CCDC: 723280.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2013年第7期1513-1520,共8页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金(No.21272045)资助项目