摘要
采用可再生资源环氧大豆油(ESBO)作为原料与二氧化碳反应合成环碳酸酯基大豆油(CSBO),再通过CSBO与乙二胺及二乙烯三胺分别反应制备非异氰酸酯聚氨酯(NIPU)预聚体;以其作为固化剂与环氧树脂E-51反应制备环氧-非异氰酸酯聚氨酯杂化涂膜。通过FT-IR对NIPU预聚物结构进行分析,证明了聚氨酯特征基团氨基甲酸酯键的生成;所制备的清漆涂膜综合性能优良,对比纯环氧体系,其耐化学性、耐磨性能更优异;同时其制备过程中不使用有毒性的异氰酸酯,安全环保。
The cyclic carbonate soybean oil（CSBO） was prepared by using the renewable resources soybean oil and carbon dioxide, then the non -isocyanate polyurethane（NIPU） prepolymer with the amino was systhesised by the reaction between the CSBO and the ethylene diamine and diethylene triamine respectively. The epoxy - NIPU hybrid coating was prepared by using NIPU as the curing agent and epoxy resin. The formation of urethanes group, the characteristic group of PU, was verified by FT - IR analysis. The hybrid coating showed high performance, especially the exc, ellent chemical resistance and wear resistance. The preparation process was safe and environment frendily, as no use of the toxic isocyanate.
出处
《涂料工业》
CAS
CSCD
北大核心
2013年第7期47-51,共5页
Paint & Coatings Industry
关键词
可再生资源
非异氰酸酯聚氨酯
杂化涂料
renewable resources
non- isocyanate polyurethane
hybrid coating
