摘要
以(NH4)6MnMo9O32.6H2O和苯并咪唑为原料,采用常规的水溶液法合成了Waugh型钼酸盐(C7H7N2)5Mn0.5(H2O)2[MnMo9O32].10H2O,并对其进行了单晶结构测定、红外光谱、固体紫外可见漫反射光谱及热重分析。晶体学参数为:单斜晶系,P2(1)/c空间群,a=10.813(6),b=15.848(9),c=36.395(2),β=95.143(10)°,V=6211.8.5(6)3,Z=2,Dc=9.841 g.cm-3,R1=0.0455,wR2=0.1005(I>2σ),GOF=1.032。
The new Waugh molybdate was obtained by reacting of (NH4 )6MnMo9O32 · 6H2O and benzimidazole in aqueous solution, and the structure and properties were characterized through single X - ray diffraction, IR, DRS and TG. The salt crystallized in the monoclnic space group a = 10. 813 (6)A, b = 15. 848 (9)A, c = 36. 395 (2)A,β = 95. 143(10)°, V=6211.8.5(6)A3, Z=2, Dc=9.841 g · cm-3, R1 =0.0455, wR2 =0. 1005(1〉2σ) , and GOF= 1. 032.
出处
《广州化工》
CAS
2013年第12期84-86,共3页
GuangZhou Chemical Industry
基金
陕西省教育厅专项基金项目(No.2010JK782)
西安石油大学大学生科研训练计划项目
关键词
WAUGH结构
合成
晶体结构
表征
Waugh structure
synthesis
crystal structure
characterization