摘要
本文对所研究的催化环氧化反应体系进行了热力学性质的有关分析,采用Joback基因贡献法估算了反应体系中相关组分的恒压热容、生成热和吉布斯自由能等热力学基础数据,并计算了相关反应的平衡常数,为其工业化生产过程的设计提供了相关基础数据。
The thermodynamics property of this catalytic epoxidation reaction system was analysed in this paper. Thermodynamic basic datas （the heat capacity at constant pressure, formation heat and gibbs free energy） of components in the reaction system were calculated by using Joback genetic contribution method. In the same time, Chemical reaction equilibrium constants were calculated. These are the important basic datas for the industrialized production process design.
出处
《计算机与应用化学》
CAS
CSCD
北大核心
2013年第6期693-698,共6页
Computers and Applied Chemistry
基金
河南省杰出人才创新基金资助项目(0121001900)
关键词
热力学数据
环己烯
催化环氧化
环氧环己烷
thermodynamic data, cyclohexene, catalytic epoxidation, cyclohexene oxide
