摘要
We adopt the post-additional thermal annealing (PATA) process to optimize the performance of the polymer solar cells (PSCs) with an active layer composed of a blend of regioregular poly (3-hexythiophene) (RR-P3HT) and fullerenes. It is found that compared with general annealing process, the crystallinity of RR-P3HT by PATA is enhanced, and the absorption peak is raised obviously at ~500 nm after PATA. With the optimized annealing conditions, the device shows an enhancement of 31% in short circuit current density, 5% in open circuit voltage (Voc), and 11% in the power conversion efficiency (PCE) compared with that of the general annealing device.
We adopt the post-additional thermal annealing (PATA) process to optimize the performance of the polymer solar cells (PSCs) with an active layer composed of a blend of regioregular poly (3-hexythiophene) (RR-P3HT) and fullerenes. It is found that compared with general annealing process, the crystallinity of RR-P3HT by PATA is enhanced, and the absorption peak is raised obviously at -500 nm after PATA. With the optimized annealing conditions, the device shows an enhancement of 31% in short circuit current density, 5% in open circuit voltage (Voc), and 11% in the power con- version efficiency (PCE) compared with that of the general annealing device.
基金
the National Basic Research Program of China (Nos.2011CBA00705, 2011CBA00706 and 2011CBA00707)
the Major Science and Technology Support Project of Tianjin (No.11TXSYGX22100)