期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

Fe(Ⅲ)Y分子筛的制备及吸附脱硫性能 被引量：1

Preparation of Fe(Ⅲ)Y molecular sieve and its adsorptive desulfurization performance
下载PDF
导出
摘要 采用离子交换法对HY分子筛进行改性制备了Fe(Ⅲ)Y分子筛,采用X-射线衍射及N2吸附-脱附技术进行表征,并测试了其吸附性能。结果表明,离子交换法制备的Fe(Ⅲ)Y分子筛比表面积等结构参数较HY分子筛的略有降低,较好的保持了分子筛的晶体结构。在吸附时间2h,吸附温度70℃,剂油比为0.04时,Fe(Ⅲ)Y分子筛的吸附脱硫率可达到68.9%。分子筛再生性能测试表明,Fe(Ⅲ)Y分子筛重复使用4次后脱硫率下降了9.1%,说明催化剂稳定性及再生性能良好。 HY molecular sieve was modified to prepare Fe（ Ⅲ）Y molecular sieve by using ion exchange method and was characterized by means of XRD and N2 adsorption-desorption. The adsorptive desulfurization performance was also studied. The results showed that surface area structure parameters of Fe（ Ⅲ）Y molecular sieve was slight- ly lower then HY molecular sieve, and the crystal structure of HY molecular sieve was maintained better. Under the optimum conditions of an adsorption temperature of 70℃, a sorbent to oil ratio of 0.04 （by volume） , and an adsorption time of 2h, the sulfur removal rates reached 68.9%. Determination of regeneration performance of Fe （ Ⅲ） Y molecular sieve was repeated four times and the desulfurization rate decreased by 9.1%, indicating good catalyst stability and regeneration properties with Fe（ Ⅲ）Y molecular sieve.
作者 房斌斌 赵华
机构地区 辽宁石油化工大学石油化工学院
出处 《化学工程师》 CAS 2012年第11期1-3,12,共4页 Chemical Engineer
基金 辽宁省博士启动基金资助项目(20081104)
关键词 Fe(Ⅲ)Y分子筛 吸附 脱硫 Fe（Ⅲ）Y molecular sieve adsorption desulfurization
分类号 TE624.9 [石油与天然气工程—油气加工工程] TQ424.2 [化学工程]
  • 相关文献

参考文献6

  • 1Lee K,Stephany R,David N.Low-eost Proeess for tow-sulfur gaso- line [ J ].Hydroearbon Proeessing, 1999,78 (5):39.
  • 2Ma X L, Sprague M, Song C S.Deep desulfurization of gasoline by seleetive adsorption over niekel-based adsorbent for fuel cell appli- cation[J ].Ind.Eng.Chem.Res., 2005,44( 15 ):5768-5775.
  • 3田福平,吴维成,蒋宗轩,杨永兴,蔡天锡,李灿.CuNaY分子筛上汽油馏分中含硫组分的选择吸附及其红外光谱研究[J].高等学校化学学报,2005,26(12):2351-2353. 被引量：19
  • 4田福平,吴维成,蒋宗轩,杨永兴,蔡天锡,李灿中国科学院大连化学物理研究所催化基础国家重点实验室.FCC汽油中含硫化合物在Ce交换的Y型分子筛上的吸附(英文)[J].催化学报,2005,26(9):734-736. 被引量：29
  • 5Takahashi A, Yang F H, Yang R T.New Sobrents for Desuluffization by [J]Ind.EngChem. Res., 2002,41 ( 10 ):2487-2496.
  • 6Yang R T,Takhaashi A,Yang F H.New Sorbents for Desulufrization of Liquid Fuels by ： -complexation [ J ].Ind.Eng.Chem.Res., 2001, 40( 26):6236-6239.

二级参考文献28

  • 1Ma X L, Sun L, Song Ch Sh. Catal Today, 2002, 77(1-2): 107.
  • 2Gu T, Mu X H, Chen X B. Huagong Jinzhan (Chem Ind Eng Progr), 2005, 24(1): 90.
  • 3Chen H Zh, Li Y D, Zhao D Sh. Huagong Keji (Sci Technol Chem Ind), 2005, 13(1): 30.
  • 4Zhang J C, Song L F, Hu J Y, Ong S L, Ng W J, Lee L Y, Wang Y H, Zhao J G, Ma R Y. Energy Convers Manage, 2005, 46(1): 1.
  • 5Jiang Z X, Liu Y, Sun X P, Shen Zh Q, Han Ch R, Li C. Cuihua Xuebao (Chin J Catal), 2003, 24(9): 649.
  • 6Mckinley S G, Angelici R J. Chem Commun, 2003, (20): 2620.
  • 7Velu S, Ma X L, Song Ch Sh. Ind Eng Chem,Res, 2003, 42(21): 5293.
  • 8Hernández-Maldonado A J, Yang R T. Ind Eng Chem,Res, 2003, 42(1): 123.
  • 9Larrubia M A, Gutièrrez-Alejandre A, Ramìrez J, Busca G. Appl Catal A, 2002, 224(1-2): 167.
  • 10Hashimoto K, Matzuo K, Kominami H, Kera Y. J Chem Soc,Faraday Trans, 1997, 93(20): 3729.

共引文献39

同被引文献18

  • 1Tao Yousheng,Kanoh H, Kaneko K. Uniform mesopore -donated zeolite Y using carbon aerogel templating [ J ]. The Journal of Physical Chemistry : B ,2003,107 ( 40 ) : 10974 - 10976.
  • 2Sato K, Nishimura Y, Honna K, et al. Role of HY zeolite meso- pores in hydrocraeking of heavy oils [ J]. Journal of Catalysis, 2001,200 (2) :288 - 297.
  • 3Lim W T,Seo S M,Kim G H,et al. Six single - crystal structures showing the dehydration, deamination, dealumination, and decom- position of NH4+ - exchanged zeolite Y (FAU) with increasing evacuation temperature. Identification of a lewis acid site [ J ]. The Journal of Physical Chemistry :C ,2007,111 (49) : 18294 - 18306.
  • 4Verboekend D, Vile G, Perez - Ramirez J. Hierarchical Y and USY zeolites designed by post - synthetic strategies [J]. Ad- vanced Functional Materials,2012,22(5 ) :916 - 928.
  • 5Tao Yousheng, Hattori Y, Matumoto A, et al. Comparative study on pore structures of mesoporous ZSM - 5 from resorcinol - formalde- hyde aerogel and carbon aerogel templating [ J ]. The Journal of Physical Chemistry : B ,2005,109 ( 1 ) : 194 - 199.
  • 6Tao Yousheng, Kanoh H,Kaneko K. ZSM - 5 monolith of uniform mesoporous channels[ J]. Journal of the American Chemical Soci- ety,2003,125 (20) :6044 - 6045.
  • 7Jin Junsu, Peng Chaoyun, Wang Jiujiang, et al. Facile synthesis of mesoporous zeolite Y with improved catalytic performance for heavy oil fluid catalytic cracking [ J ]. Industrial & Engineering Chemistry Research ,2014,53 ( 8 ) :3406 - 3411.
  • 8Liu Baoyu, Chen Fei,Zheng Liming, et al. Synthesis and structural properties of hierarchically structured aluminosilicates with zeolite Y (FAU) frameworks [ J]. RSC Advances, 2013, 3 (35): 15075 - 15084.
  • 9Wang Xiaoxing, Li Gang, Wang Weihai, et al. Synthesis, charac- terization and catalytic performance of hierarchical TS - 1 with carbon template from sucrose carbonization [ J ]. Microporous and Mesoporous Materials ,2011,142 ( 2 ) :494 - 502.
  • 10Ginter D M,Went G T, Bell A T,et al. A physicochemical study of the ageing of colloidal silica gels used in zeolite Y synthesis [ J ]. Zeolites, 1992,12 (6) :733 - 741.

引证文献1

二级引证文献3

化学工程师
2012年 第11期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部