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一维链状配合物[Cd(mbix)Cl_2]_n的水热合成及其晶体结构 被引量：1

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摘要 以Cd(OAc)_2·2H_2O和2,3-吡嗪二甲酸、1,3-双(咪唑基-1-甲基)苯(mbix)为原料,采用水热法合成了一维链状配位聚合物[Cd(mbix)Cl_2]_n,并对配合物进行了元素分析、红外光谱、荧光光谱和X-射线单晶衍射测定.该配合物属于三斜晶系,P-I空间群,a=7.887(3),b=8.856(3),c=11.080(3)(?),α=106.753(5)°,β=91.002(5)°,γ=107.161(5)°,V=703.6(4)(?)~3,Z=1,D_c=1.557g/cm^3,μ=0.999mm^(-1),F(000)=334,R_1=0.0457,wR_2=0.1218.
作者 纪建业 李忠平 李秀梅 牛艳玲 王志涛
机构地区 通化师范学院化学学院
出处 《通化师范学院学报》 2013年第6期22-23,43,共3页 Journal of Tonghua Normal University
基金 吉林省教育厅资助课题(吉教科合字[2013]第384号)
关键词 1 3-双(咪唑基-1-甲基)苯 水热合成 晶体结构
分类号 O631 [理学—高分子化学]
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参考文献10

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同被引文献5

  • 1Rao C N R, Natm'ajan S, Vaidhyanathan R. Metal Carboxylates with Open Architectures [ J ]. Angew Chem Int Ed. , 2004,43 ( 12 ) : 1466 - 1496.
  • 2Konar S,Manna S C, Zangrando E, et al. Crystal Structure and Magnetic Behavior of a Copper(II) - ( Pyrazine 2,3 - dicarboxylate) Co- ordination Polymer:3 D Architecture Stabilized by H -bonding[ J ]. Inorg. Chim. Acta. ,2004,357 : 1593 - 1597.
  • 3Dobrzan ska L. Catena - Poly [ [ Zinc ( II ) - bis [ Ix - 1, 3 - Bis ( Imidazol - 1 - ylmethyl) Benzene - K2 N3 : N3'] ] dinitrate methanol sol-vate ] [ J ]. Acta Cryst. ,2009, E65 : 1326 - 1327.
  • 4Sheldrick G M. SHELXS 97. Program for the Solution of Crystal Structure [ M ]. Germany : University of Cttingen, 1997.
  • 5Sheldrick G M. SHELXS 97. Program for the Refinement (ff Crystal Structure[ M]. Germany: University of G6ttingen,1997.

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通化师范学院学报
2013年 第6期

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