期刊文献+

利用X光散射实验研究C-S-H的微观结构

The Microstructure Study on C-S-H by X-ray Scattering
原文传递
导出
摘要 为了了解波特兰水泥中的水化硅酸钙(C-S-H)的微观结构,对有无含添加剂superplasticizers(SPs)、从5天到68天的不同老化时间的波特兰水泥样品的X光散射实验,实验数据结果分析表明C-S-H中钙硅层间距的大小是0.98±0.01nm,结果说明波特兰水泥样品中C-S-H中钙硅层间距与样品是否含SPs以及样品的老化时间无关。 In order to understand the microstructure of the calcium silicate hydrate (C-S- H) , the samples of Portland cement paste with/without superplasticizers (SPs) at differ- ent aging time from 5 days to 68 days were studied by the X-ray scattering. The experi- mental data analysis shows that the interlayer space between calcium silicate layers within C-S-H is 0.98±0.01 nm. The result indicates that the interlayer space between calcium silicate layers within C-S-H in Portland cement is constant regardless of what aging time is and whether the paste is with/without SPs.
出处 《光散射学报》 北大核心 2013年第2期142-146,共5页 The Journal of Light Scattering
关键词 微观结构 X光散射 C-S-H microstructure X-ray scattering C-S-H
  • 相关文献

参考文献19

  • 1Fratini Emiliano,Ridi Francesca,Chen Sow-Hsin,etal.Hydration water and microstructure in calcium sil-icate and aluminate hydrates[J].J Phys CondensMatter,2006,18,S2467-S2483.
  • 2Ridi Francesca,Luciani Paola,Fratini Emiliano,etal.Water confined in cement pastes as a probe of ce-ment microstructure evolution[J].J Phys Chem B,2009,113,3080-3087.
  • 3Livingston R A,Bumrongjaroen W,Allen A J.Thefractal ratio as a metric of nanostructure developmentin hydrating cement paste.nanotechnology in con-struction[M].Nanotechnology in Construction 3Pro-ceedings of the NICOM3,Springer Berlin Heidelberg,2009,part2.101-106.
  • 4Skinner L B,Chae S R,Benmore C J,et al.Nano-structure of calcium silicate hydrates in cements[J].Phys Rev Lett,2010,104,195502.
  • 5Meral Cagla,Benmore C J,Monteiro Paulo J M.Thestudy of disorder and nanocrystallinity in C-S-H,sup-plementary cementitious materials and geopolymers u-sing pair distribution function analysis[J].Cementand Concrete Reseach,2011,41:696-710.
  • 6Li Hua,Chiang Wei-Shan,Fratini Emiliano,et al.Dynamic crossover in hydration water of curing cementpaste:the effect of superplasticizer[J].J Phys Con-dens Matt,2012,24:064108.
  • 7Fujii Kinjiiro,Kondo Wakichi.Communications of theamerican ceramic society estimimation of thermochemi-cal data for calcium silicate hydrate(C-S-H)[J].J AmCeram Soc,1983,66(12):C220-C240.
  • 8Taylor Harry F W.Proposed structure for clacuim sili-cate hydrate gel[J].J Am Ceram Soc,1986,69:464-467.
  • 9Jennings Hamlin M.A model for the microstructure ofcalcium silicate hydrate in cement paste[J].Cem ConcrRes,2000,30:101-106.
  • 10Jennings Hamlin M.Refinements to colloid model ofC-S-H in cement:CM-Ⅱ[J].Cement and ConcreteResearch,2008,38:275-289.

二级参考文献38

  • 1赵庆新,孙伟,陈惠苏,郑克仁,金祖权.应用纳米压痕技术测试水泥粒子的弹性模量[J].武汉理工大学学报,2006,28(8):31-33. 被引量:3
  • 2FUJII K, KONDO W. Estimation of thermochemical data for calcium silicate hydrate (C-S-H) [J]. J Am Ceram Soc, 1983, 66(12): C220- C240.
  • 3TAYLOR H F W. Proposed structure for calcium silicate hydrate gel [J]. J Am Ceram Soc, 1986, 69: 464-467.
  • 4TAYLOR H F W. Nanostructure of C-S-H: Current states [J]. Adv Cem Base Mater, 1993, 1: 38-46.
  • 5TAYLOR H F W. The Chemistry of Cement [M]. London: Academic Press, 1992: 142.
  • 6RICHARDSON I, GROVES G W. Models for the composition and structure of calcium silicate hydrate (C-S-H) gel in hardened tricalcium silicate pastes [J]. Cem Concr Res, 1992, 22(6): 1001-1010.
  • 7XU Z, VIEHLAND D. Observation of a mesostructure in calcium silicate hydrate gels of portland cement [J]. Phys Rev Lett, 1996, 77(5): 952-955.
  • 8VIEHLAND D, LI J F, YUAN L J, et al. Mesostructure of calcium silicate hydrate (C-S-H) gels in Portland cement paste: Short-range ordering, nanocrystallinity, and local compositional order [J]. J Am Cerarn Soc, 1996, 79 (7): 1731-1744.
  • 9ZHANG Xiaozhong, CHANG Wenyi, ZHANG Tiejun, et al. Nanostructure of calcium silicate hydrates gels in cement paste [J]. J Am Ceram Soc, 2000, 83(10): 2600-2604.
  • 10CONSTANTINIDES G, ULM F J, VLIET K V. On the use of nanoin- detation for cementitious materials [J]. Mater Construc, 2003, 36: 191-196.

共引文献20

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部