二聚5,6-二氧代-1,10-邻菲咯啉配合物的合成及结构分析

Synthesis and Structural Analysis of a Two-polymerization of 5,6-dioxo-1,10-Phenanthroline Monohydrate Coordination Polymer

利用水热反应合成了聚5,6-二氧代-1,10-邻菲咯啉配合物晶体。同时利用X射线单晶衍射对标题化合物进行了表征。晶体数据:单斜晶系,空间群P2(1)/c,a=1.7365(4)nm,b=1.0961(2)nm,c=1.4424nm,β=111.75(3)°,V=2.5501(9)nm3,Dc=1.470mg/m3,Z=4,F(000)=1168,最终残差因子R1=0.0445,wR2=0.1053,对于全部数据R1=0.0915,wR2=0.1198。

a Two-Polymerization of 5,6-dioxo-1,10-Phenanthroline monohydrate Coordination Polymer has been synthesized through hydrothermal reaction and structurally characterized by single crystal X-ray diffraction method. In addition, the results of IR and 1H NMR analysis were presented. Crystal data ： tetragonal, space group P2（1）/c,a=1.7365（4）nm,b=1.0961（2）nm,c=1.4424nm,β=111.75（3）°,V=2.5501（9）nm3,Dc=1.470mg/m3,Z=4,F（000）=1168, final R indices [I 〉2sigma（I） ] R1 = 0.0445,wR2 = 0. 1053,for all reflections R1= 0.0915, wR2 = 0. 1198.