A {Ni_7} cluster-containing sandwich-type phosphotungstate functionalized by organic bisphosphonate ligands and its two-dimensional supramolecular structure 被引量：3

A {Ni_7} cluster-containing sandwich-type phosphotungstate functionalized by organic bisphosphonate ligands and its two-dimensional supramolecular structure

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摘要 A {NIT] cluster-substituted sandwich-type phosphotungstate Na10（NH4）4[{（B-a-PW9034）Ni3 （OH）（H20）2（HAle））2Ni].22H20 （1） was synthesized using the conventional aqueous solution method. Compound 1 represents the first nickel-containing sandwich-type polyoxometalate functionalized by bisphosphonate ligands. Further, the sandwich-type polyoxoanions aggregated via the H-bonding interactions into a two-dimensional （2D） suoramolecular framewnrk. A {NIT] cluster-substituted sandwich-type phosphotungstate Na10（NH4）4[{（B-a-PW9034）Ni3 （OH）（H20）2（HAle））2Ni].22H20 （1） was synthesized using the conventional aqueous solution method. Compound 1 represents the first nickel-containing sandwich-type polyoxometalate functionalized by bisphosphonate ligands. Further, the sandwich-type polyoxoanions aggregated via the H-bonding interactions into a two-dimensional （2D） suoramolecular framewnrk.

作者 Ying Zhang Xin-Bao Han Zhi-Ming Zhang Zhu-Jun Liu En-Bo Wang

机构地区 Key Laboratory of Polyoxometalate Science of Ministry of Education

出处《Chinese Chemical Letters》 SCIE CAS CSCD 2013年第7期581-584,共4页 中国化学快报（英文版）

基金 supported by the National Natural Science Foundation of China(No.21101022) Fundamental Research Funds for the Central Universities(No.10QNJJ009)

关键词 Supermolecule Polyoxometalate Sandwich Organic-inorganic hybrid Supermolecule Polyoxometalate Sandwich Organic-inorganic hybrid

分类号 O627.51 [理学—有机化学]

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Chinese Chemical Letters

2013年第7期

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