摘要
本文把 Wade规则推广应用于稠合型硼烷和稠合型金属碳硼烷中 ,导出计算它们价电子数 (NVE)的公式。对于稠合型硼烷 ,本文公式与唐敖庆等的拓扑结构规则的计算结果相同。但本文公式的适用范围比上述两个规则广。
The extended application of Wade's rule to joined type boranes and metallocarboranes was discussed in this article.A new formula for calculating the number of valence electrons was derived.The calculated results of joined type boranes are in agreement with that obtained from the topological structure rule proposed by Tang Au chin et al.,but the new formula can be used in a more wide range.
出处
《化学研究与应用》
CAS
CSCD
2000年第5期482-486,共5页
Chemical Research and Application
基金
黑龙江省教委科研基金
关键词
Wada规则
稠合型硼烷
稠合型金属碳硼烷
NVE
Wade's rule
joined type boranes
joined type metallocarboranes
metallorganic compounds
