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添加稀土氧化物助剂的CeO_2-ZrO_2固溶体的储氧性及热稳定性研究 被引量:6

STUDY OF OXYGEN STORAGE PROPERTIES AND THERMAL STABILITY ON REO MODIFIED CeO_2-ZrO_2 SOLID SOLUTIONS
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摘要 Three kinds of REO modified CeO 2 ZrO 2 solid solutions were prepared by co precipitate method.TPR and XRD measurements have been used to characterize the effect of REO on the thermal stability and oxygen storage properties of CeO 2 ZrO 2 solid solutions,comparison being made with unmodified CeO 2 ZrO 2 solid solutions.The results indicated that the addition of REO to CeO 2 ZrO 2 solid solutions obviously improved the oxygen storage properties of the three kinds of solid solutions calcinated at 773K.Except for Zr rich solid solutions,the modified CeO 2 ZrO 2 solid soltuions calcinated at 1173K show higher thermal stability and oxygen storage properties than unmodified solid solutions. Three kinds of REO modified CeO 2 ZrO 2 solid solutions were prepared by co precipitate method.TPR and XRD measurements have been used to characterize the effect of REO on the thermal stability and oxygen storage properties of CeO 2 ZrO 2 solid solutions,comparison being made with unmodified CeO 2 ZrO 2 solid solutions.The results indicated that the addition of REO to CeO 2 ZrO 2 solid solutions obviously improved the oxygen storage properties of the three kinds of solid solutions calcinated at 773K.Except for Zr rich solid solutions,the modified CeO 2 ZrO 2 solid soltuions calcinated at 1173K show higher thermal stability and oxygen storage properties than unmodified solid solutions.
出处 《化学研究与应用》 CAS CSCD 2000年第5期543-546,共4页 Chemical Research and Application
基金 四川省计委重大项目资助
关键词 CeO2-ZrO2固溶体 储氧性 汽车尾气净化 催化剂 REO CeO 2 ZrO 2 solid soltuions oxygen storage properties thermal stability
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参考文献1

  • 1Yao H C,Journal of catalysis,1984年,86期,25页

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