连苯三酚氧化产物及其金属配合物的合成及表征

Synthesis and Characterization of the Oxidation Product of the 1,2,3-trihydroxybenzene and Its Metalic Complexes

在abinitio量子化学研究的基础上 ,研究了连苯三酚的氧化反应 ,并合成了连苯三酚氧化产物与水合肼的缩合物及其金属配合物 ,用IR、Raman光谱和热重分析 ,确定了配合物的组成及THBO的可能结构。

The oxidation reaction mechanism of the 1,2,3 -t rihydroxybenzene was studied by the Ab initio calculation of the quantum chemist ry. The derivative of the hydrazine and THBO(the reaction product of the 1,2,3- trihydroxybenzene and H 2O 2) and its metal complexes were synthesized and cha racterized by the IR,Raman spectrum and thermogravimetric analysis. The composit ion of these complexes and the possible structure of THBO were confirmed.