[PMo_9V_3O_(40)]^(6-)硫代物的合成及光谱研究

Synthesis and Spectroscopic Studies of the Oxothio Heteropolyanio n of [PMo_9V_3O_(40)]^(6-)

通过H2 S与杂多化合物 (NH4 ) 4H2 [PM9V3 O4 0 ]·10H2 O在DMF中反应合成了其硫代产物 。

Some compounds were obtained through addition H 2S to the heteropoly-compound (NH 4) 4H 2[PMo 9V 3O 40]·10H 2 O in dimethyformamide.The FTIR spectrum and NIR FT-Raman spectrum of these comp ounds were investigated.The spectroscopic studies of the compound Ⅱshowed that it is a oxothio heteropoly-compound.