摘要
A new thiolate-bridged diiron complex with two mono-coordinated azido ligands, [Cp*Fe(kt-SMe)N3]2 (Cp^* = η^5-C5Me5), was synthesized from [Cp*Fe(η-SMe)MeCNMPF6]2 and NaN3 in a bi-solvent system of acetone and methanol. X-ray crystal structural analysis shows that the compound belongs to the orthorhombic Fdd2 space group, with a = 14.3771(15), b = 71.424(8), c = 9.7010(10)A, V = 9961.7(18) A3, C22H36Fe2N6S2, Mr = 560.39, Dc = 1.495 g/cm^3, F(000) = 4704,μ(MoKa) = 1.355 mm-I and Z = 16. The compound consists ofa di(u-thiolate)diiron unit {Cp*Fe(p-SMe)}2, in which each iron is coordinated by a terminal azido ligand. Magnetic characterizations show spin canting behavior for the title compound.
A new thiolate-bridged diiron complex with two mono-coordinated azido ligands, [Cp*Fe(kt-SMe)N3]2 (Cp^* = η^5-C5Me5), was synthesized from [Cp*Fe(η-SMe)MeCNMPF6]2 and NaN3 in a bi-solvent system of acetone and methanol. X-ray crystal structural analysis shows that the compound belongs to the orthorhombic Fdd2 space group, with a = 14.3771(15), b = 71.424(8), c = 9.7010(10)A, V = 9961.7(18) A3, C22H36Fe2N6S2, Mr = 560.39, Dc = 1.495 g/cm^3, F(000) = 4704,μ(MoKa) = 1.355 mm-I and Z = 16. The compound consists ofa di(u-thiolate)diiron unit {Cp*Fe(p-SMe)}2, in which each iron is coordinated by a terminal azido ligand. Magnetic characterizations show spin canting behavior for the title compound.
基金
supported by NNSFC (21231003, 20972023, 21076037)