摘要
The thermal properties of two heteropoly complexes a- [ (C7H15) 4N]3H2[SiW11 (NbO2) O39] H2O and a-[ (C7H15)4N]4 [PW11 (NbO2). O39] H2O were studied by means of TG DTA and DSC. The activation energies and reaction orders of the thermal decomposition reaction of these complexes have been calculated.
The thermal properties of two heteropoly complexes a- [ (C7H15) 4N]3H2[SiW11 (NbO2) O39] H2O and a-[ (C7H15)4N]4 [PW11 (NbO2). O39] H2O were studied by means of TG DTA and DSC. The activation energies and reaction orders of the thermal decomposition reaction of these complexes have been calculated.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2000年第5期815-820,共6页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金资助项目!(No.29471009)
关键词
过氧铌杂多配合物
活化能
反应级数
热分解
peroxonibium heteropoly complexes
thermal analysis
reaction order
activation energy
