摘要
A novel Microporous decatungstate was synthesized by using cationic l,10-diaminode-cane as template under mile chemical donditions,This material was construdted from hoghly ordered hexahonal array of 1,10-diaminodecane and decatungstate polyanions.HR-TEM image ahowded that the decatungstate polyanions"packed"around the l,10-diaminodecane moledules.XRD pattern confirmed its hexagonal array(a=b=1.718nm,cunaknown).Atdlplate mechanosm was pro-posed to explain its formation prodess.It is evidenced that l,10-diaminodecane molecules play a crucial role in templating the inorganic framework.the cationic diaminodecane molecules "bond"decatungstate polyanions on esch end via supermolecular interation and thus form bolarform struc-ture units.These units pack together and ahexagonal phasa is constructed.
A novel Microporous decatungstate was synthesized by using cationic l,10-diaminode-cane as template under mile chemical donditions,This material was construdted from hoghly ordered hexahonal array of 1,10-diaminodecane and decatungstate polyanions.HR-TEM image ahowded that the decatungstate polyanions'packed'around the l,10-diaminodecane moledules.XRD pattern confirmed its hexagonal array(a=b=1.718nm,cunaknown).Atdlplate mechanosm was pro-posed to explain its formation prodess.It is evidenced that l,10-diaminodecane molecules play a crucial role in templating the inorganic framework.the cationic diaminodecane molecules 'bond'decatungstate polyanions on esch end via supermolecular interation and thus form bolarform struc-ture units.These units pack together and ahexagonal phasa is constructed.
出处
《物理化学学报》
SCIE
CAS
CSCD
北大核心
2000年第9期769-771,共3页
Acta Physico-Chimica Sinica
基金
国家自然科学基金!(批准号:59932040)
中国科学院资助项目
关键词
十聚钨酸
多孔材料
癸二胺
模板合成
decatungstate,microporous materials,l,10-diaminodecane,templatig synthesis