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时间分辨红外发射光谱研究C_2H_3+NO反应体系 被引量:4

Reaction of C2H3+ NO Studied by Time- Resolved Emission Spectroscopy
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摘要 The elementary reaction of C2H3+ NO has been reported for the first time in this paper.C2H3 radical was produced by laser photolysis of vinyl bromide at 248 nm.Vibrationally excited reaction products H2CO,NCO and HCN were observed.Two exothermic reaction channels leading to HCN+ H2CO and CH3+ NCO are identified. The elementary reaction of C2H3+ NO has been reported for the first time in this paper.C2H3 radical was produced by laser photolysis of vinyl bromide at 248 nm.Vibrationally excited reaction products H2CO,NCO and HCN were observed.Two exothermic reaction channels leading to HCN+ H2CO and CH3+ NCO are identified.
出处 《物理化学学报》 SCIE CAS CSCD 北大核心 2000年第9期776-778,共3页 Acta Physico-Chimica Sinica
基金 国家自然科学基金!(29773052) 科技部973项目
关键词 NO C2H3 FTIR 基元反应 NO, C_2H_3, Reaction, FTIR
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  • 1朱起鹤,化学物理学报,1993年,6卷,87页

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  • 1Xing Wang Wang~1 Jin Hui Yuan~1 Ru Gang Zhang~1 Li Xia Guo~1 Yong Xie~2 Hong Xie~1 ~1Department of Biotherapy,Shanghai Institute of Cell Biology,Chinese Academy of Sciences,Shanghai 200031,China ~2Department of Biology,Hong Kong University of Science and Technology,ChinaDr.Xing Wang Wang earned Ph.D.from Shanghai Institute of Materia Medical,Chinese Academy of Sciences in 1997.Now a professor at Shanghai Institute of Cell Biology,Chinese Academy of Sciences..Antihepatoma effect of alpha-fetoprotein antisense phosphorothioate oligodeoxyribonucleotides in vitro and in mice[J].World Journal of Gastroenterology,2001,7(3):345-351. 被引量:21
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