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杀菌剂戊菌唑的合成新工艺研究 被引量:1

Novel Synthesis of Fungicide Penconazole
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摘要 以2,4-二氯苯丁酮为起始原料,经过环合、重排、还原、磺化、缩合5步制得杀菌剂1-[2-(2,4-二氯苯基)戊基]-1H-1,2,4-三唑,总收率达到了67%。 1-[2-(2,4-Dichlorophny)pentyl]-1H-1,2,4-triazole(Penconazole) was prepared in overall yield of 67% via cyclization,rearrangement,reduction,sulfonation and condensation starting from 2,4 dichlorobutyrophenone.
出处 《精细化工中间体》 CAS 2013年第3期18-19,32,共3页 Fine Chemical Intermediates
关键词 戊菌唑 2 4-二氯苯丁酮 合成 penconazole 2 4-Dichlorobutyrophenone synthesis
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参考文献8

  • 1沙家骏 张敏恒 姜雅君.国外新农药品种手册[M].北京:化学工业出版社,1993..
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  • 7王进,陈华,廖文斌.戊菌唑的合成工艺研究[J].浙江化工,2006,37(2):4-4. 被引量:2
  • 8刘丽,李翔.杀菌剂戊菌唑的合成[J].现代农药,2006,5(1):9-10. 被引量:2

二级参考文献9

  • 1Keith C,Geoffrey L B,Peter H N.Volatile Analogues of Penconazole and Their Activity against the Take-All Fungus,Gaeumannomyces Graminis var.Tritici[J].Pesticide Science,1991,31(2):185-196.
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  • 4Wetter H D,Baumeister P.Method for the Production of 1-(2-(,4- Dichlorphenyl)pentyl)-1H-1,2,4-triazole and Hydrazone or Hydra- zine-derivatives:EP,0097617[P].1984-01-04.
  • 5Maier L D,Kunz W D.Process for the Preparation of Phenylethyl Triazoles:EP,0063099[P].1982-10-20.
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  • 7沙家俊.国外新农药品种手册[M].北京:化学工业出版社,1993.255-257.
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