期刊文献+

锂离子电池负极材料SnO_2的制备及其性能研究

Synthesis and characterization of SnO_2 anode material for lithium-ion batteries
原文传递
导出
摘要 以NaOH为沉淀剂,聚乙二醇400(PEG400)为分散剂,采用改进的化学沉淀法制备了前驱体粉末Sn(OH)2,在不同温度下煅烧得到了SnO2纳米颗粒。运用X射线衍射、扫描电镜、恒流充放电、循环伏安法等手段对所制材料的结构、表面形貌和电化学性能进行了研究。结果表明:采用改进的化学沉淀法可以得到平均粒度为80nm左右的SnO2纳米颗粒,其中700℃下煅烧合成的SnO2性能最佳,其首次放电比容量和充电比容量分别为1 576.3mAh/g和836.7 mAh/g,首次库仑效率为53.1%。经过20次循环充放电后,其比容量仍有411.4 mAh/g。 A series of nano-size SnO2 samples were synthesized by the pyrolysis of Sn(OH)2 precursor at different temperature via a modified chemical precipitation method,with sodium hydroxide as precipitation agent and polyethylene glycol 400(PEG400) as dispersing agent.The crystalline structure,grain morphology and electrochemical performance of the prepared powders were characterized by X-ray diffraction(XRD),scanning electron microscope(SEM),galvanostatic charge/discharge(DC) and cyclic voltammetry(CV) methods.The results show that the average size of SnO2 nanoparticles are about 80 nm.And the samples prepared at 700 ℃ exhibit the best electrochemical performance,the initial discharge and charge specific capacity are 1 576.3 mAh/g and 836.7 mAh/g,respectively.The first coulombic efficiency is 53.1% and the specific capacity still retain at a high level of 411.4 mAh/g after 20 cycles.
出处 《电子元件与材料》 CAS CSCD 北大核心 2013年第8期14-17,共4页 Electronic Components And Materials
基金 国家科技支撑计划项目(No.2012BAK26B04) 广东省科技计划项目(No.2010A011300041 No.2011B050300017) 广东省高等学校科技创新重点项目(No.粤财教〔2011〕473号)
关键词 锂离子电池 负极材料 SNO2 共沉淀法 比容量 库仑效率 lithium-ion battery anode material SnO2 co-precipitation method specific capacity coulombic efficiency
  • 相关文献

参考文献3

二级参考文献30

  • 1齐智,吴锋.用于锂离子电池负极SnO_2-MCMB复合材料的研究[J].现代化工,2004,24(11):40-42. 被引量:8
  • 2张汉平,付丽君,吴宇平,吴浩青,高村勉.锂离子电池负极材料的研究进展[J].电池,2005,35(4):274-275. 被引量:13
  • 3卢献忠,黄峰,雷雪梅,李思.溶胶-凝胶法制备纳米SnO_2[J].武汉科技大学学报,2006,29(1):20-21. 被引量:10
  • 4Park Y S,Bang H J,Oh S M,et al.Effect of carbon coating on thermal stability of natural graphite spheres used as anode materials in lithium-ion batteries[J].J Power Sources,2009,190(2):553-557.
  • 5Courtney I,McKinnon W R,Dahn J R.On the aggregation of tin in SnO composite glasses caused by the reversible reaction with lithium[J].J Electrochem Soc,1999,146(1):59-68.
  • 6Zhu J J,Liu Z H,Aruna S T,et al.Sonochemical synthesis of SnO2 nanaparticles and their preliminary study as Li insertion electrodes[J].Chem Mater,2000,12(9):2 557-2 566.
  • 7Chen G,Wang Z Y,Xia D G.One-pot synthesis of carbon nano-tube @ SnO2-Au coaxial nanocable for lithium-ion batteries with high rate capability[J].Chem Mater,2008,20(22):6 951-6 956.
  • 8Courtney I,Daha J R.Key factors controlling the reversibility of the reaction of lithium with SnO2 and Sn2BPO6 glass[J].J Electrochem Soc,1997,144(6):2 943-2 948.
  • 9Sun X M,Liu J F,Li Y D.Oxides@C core-shell nanostructures:one-pot synthesis,rational conversion,and Li storage property[J].Chem Mater,2006,18(15):486-494.
  • 10I A Courtney,J R Dahn.Electrochemical and in Site X-ray Diffraction Studies of the Reaction of Lithium with Tin Oxide Composites[J].J Electrochem Soc,1997,144:2 045-2 050.

共引文献13

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部