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PTA装置氧化设备的模拟研究和应用

Simulation study and application of oxidation equipment in PTA plant
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摘要 对PTA装置氧化单元中PX氧化反应器的反应机理和结晶器中的对苯二甲酸成核和生长规律分别作了深入的研究。利用PRO/II模拟软件建立了实用的PX氧化反应器和结晶器模拟模块。旋转真空过滤机、干燥机、薄膜蒸发器、高压吸收塔、常压吸收塔、汽提塔和溶剂脱水塔等设备也进行了模拟研究,建立了实用的各设备模拟模块。经对比,模拟结果与参考数据的偏差在可接受的范围内,可以应用于PTA装置的工程设计。 The reaction mechanism of p-xylene oxidation reactor in PTA plant oxidation unit and the nucleation and growth law of TA in crystallizer was studied in detail. By using PRO/Ⅱ simulation software, practical PX oxidation reator and crystallizer simulation modules has been established. Also, simulation study was carried out such as rotary vacuum filter, dryer, film evaporator, high pressure absorption column, atmospheric absorption column, stripper and solvent dehydration tower. Practical simulation modules for each equipment were developed. By comparison, the de- viation between the simulation results and reference data is within the acceptable range. The simulation modules can be applied to the engineering design of PTA plant.
作者 熊献金
出处 《聚酯工业》 CAS 2013年第4期35-40,共6页 Polyester Industry
关键词 PTA 氧化 模拟研究 PTA oxidation simulation study
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  • 1Paretnheimer W. Methodology and Scope of Metal/Bromide Autoxidation of Hydrocarbons.CatalysisToday,1995,23:69-158.
  • 2Partenheimer W.Catalysis of Organic Reactions,Chapter 20.New York:Marcel Dekker,1990.
  • 3Cincotti A,Orru R,Broi A,Cao G. Effect of Catalyst Concentration and Simulation of Precipitation Processes on Liquid-phase Catalytic Oxidation of p-Xylene to Terephthalic Acid.Chemical Engineering Science,1997:4205-4213.
  • 4Cincotti A,Orru R,Broi A,Cao G. Kinetics and Related Engineering Aspects of Catalytic Liquid-phase Oxidation of p-Xylene.Catalysis today,1999,52:331-347.
  • 5Roger A Sheldon, Jay K Kochi. Metal-catalyzed Oxidation of Organic Compounds. New York: Acadejic Press Inc. , 1981.
  • 6Scott E J Y, Chester A W. Kinetics of the Cobalt-catalyzed Autoxidation of Toluene in Acetic Acid. The Journal of Physical Chemistry, 1978, 76:1520--1524.
  • 7Ou Canqi(区灿棋),Lü Dewei(吕德伟).Engineering and Process of Oxidation Reaction in Petrochemical(石油化工氧化反应工程与工艺).Beijing:Sinopec Press,1990.

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