固体碱KF/Al_2O_3在过渡金属催化的偶联反应中应用研究进展

Progress of Research on KF/Al_2O_3 Used as a Solid Base in Transition-metal Catalyzed Coupling Reactions

自Clark和Ando的等发现KF/Al2O3的特殊性能以来,KF/Al2O3在诸多类型的有机反应中得到应用,并取得了满意的结果。近年来,化学科研工作者不断地对其进行深入的研究,使其在更多有机合成领域得到应用。综述了近年来固体碱KF/Al2O3在过渡金属催化的偶联反应中应用的研究进展。

Since the introduction of alumina-supported potassium fluoride（KF） as a solid heterogeneous base by Clark, Ando et al, diverse organic reactions catalysed by it were reported in the literature. Even after decades of its first observationKF/Al2O3 still continues to receive immense limelight. The advances in transition-mettal catalyzed coupling reactions using KF/Al2O3 as solid base were reviewed.