摘要
使用的代替的酞酸酐(trifluoromethyl ) 的有效催化铜的 trifluoromethylation trimethylsilane (Me3SiCF3 ) 作为亲核的 trifluoromethylating 试剂面对 1,10-phenanthroline 和 KF，由与水熄灭反应混合列在后面被开发了。可能的机制被建议。
An efficient copper-catalyzed trifluoromethylation of substituted phthalic anhydrides using （trifluoromethyl） trimethylsilane （Me3SiCF3） as a nucleophilic trifluoromethylating reagent in the presence of 1,10-phenanthroline and KF, followed by quenching the reaction mixture with water has been developed. A possible mechanism was suggested.
基金
Acknowledgement We are grateful for financial supports from the National Natural Science Foundation of China （Nos. 21072057, 21272070）, the 973 Program （No. 2010CB126101）, the Key Project in the National Science ＆ Technology Pillar Program of China in the twelfth five-year plan period （No. 2011BAE06B05）.
