摘要
Efficient room temperature phosphorescence (RTP) is rarely observed in pure organic luminogens. However, we have newly observed that benzil and its derivatives are nonluminescent in solvents and thin layer chromatography (TLC) plates, but become highly phosphorescent in crystal state at room temperature, exhibiting typical crystallization-induced phosphorescence (CIP) characteristics. The CIP phenomenon is ascribed to the restriction of intramolecular rotations in crystals owing to effective intermolecular interactions. Such intermolecular interactions greatly rigidify the molecular conformation and significantly decrease the nonradiative deactivation channels of the triplet excitons, thus giving boosted phosphorescent emission at room temperature.
Efficient room temperature phosphorescence （RTP） is rarely observed in pure organic luminogens. However, we have newly observed that benzil and its derivatives are nonluminescent in solvents and thin layer chromatography （TLC） plates, but become highly phosphorescent in crystal state at room temperature, exhibiting typical crystallization-induced phosphorescence （CIP） characteristics. The CIP phenomenon is ascribed to the restriction of intramolecular rotations in crystals owing to effective intermolecular interactions. Such intermolecular interactions greatly rigidify the molecular conformation and significantly decrease the nonradiative deactivation channels of the triplet excitons, thus giving boosted phosphorescent emission at room temperature.
基金
the National Natural Science Foundations of China (21104044)
the National Basic Research Program of China (973 Program, 2013CB834701 and 2013CB834704)
the Ph.D. Programs Foundation of Ministry of Education of China (20110073120040)
the Shanghai Leading Academic Discipline Project (B202). W.Z.Y. thanks the Start-up Foundation and SMC-Chenxing Young Scholar Pro- gram of Shanghai Jiao Tong University.
关键词
室温磷光
苯偶酰
诱导
结晶
相互作用
薄层色谱法
三线态激子
分子间
crystallization-induced phosphorescence, room temperature phosphorescence, benzils, intermolecular interactions
