摘要
This paper described the fluoride removal from water using a new adsorbent namely mixed rare earths modified chitosan （CR）. Mixed rare earths mainly contained La followed by Ce which was analyzed by inductively coupled plasma mass spectrometry （ICP-MS）. La（III）-modifled chitosan （CL） was also prepared as control. For the batch technique, the effects of various parameters such as contact time, pH, adsorbent dose, initial fluoride concentration and co-ions on fluoride adsorption were studied. Fourier trans- form infrared spectroscopy （FTIR） and X-ray diffraction （XRD） were used to characterize adsorbents. It was observed that the fluo- ride adsorption capacity of CR （3.72 mgF-/g） was higher than CL （3.16 mgF-/g） at 2 h. The presence of co-ions such as bicarbonate and carbonate greatly affected the fluoride adsorption from water. Characterization experiments indicated the successful chelation between mixed rare earths and chitosan. The possible fluoride adsorption mechanism of CR was explained by a chemical reaction.
This paper described the fluoride removal from water using a new adsorbent namely mixed rare earths modified chitosan （CR）. Mixed rare earths mainly contained La followed by Ce which was analyzed by inductively coupled plasma mass spectrometry （ICP-MS）. La（III）-modifled chitosan （CL） was also prepared as control. For the batch technique, the effects of various parameters such as contact time, pH, adsorbent dose, initial fluoride concentration and co-ions on fluoride adsorption were studied. Fourier trans- form infrared spectroscopy （FTIR） and X-ray diffraction （XRD） were used to characterize adsorbents. It was observed that the fluo- ride adsorption capacity of CR （3.72 mgF-/g） was higher than CL （3.16 mgF-/g） at 2 h. The presence of co-ions such as bicarbonate and carbonate greatly affected the fluoride adsorption from water. Characterization experiments indicated the successful chelation between mixed rare earths and chitosan. The possible fluoride adsorption mechanism of CR was explained by a chemical reaction.
基金
supported by National Natural Science Foundation of China (31101330)
International Joint Research Program(2010DFA31330)
Public Science and Technology Research Funds Projects of Ocean (201005020-6)
