摘要
二僵硬 macrocyclic 基于 CTV 的多孔的器官的聚合物， Click-POP-1 和 Click-POP-2，被 cyclotriveratrylene 类似物的按反应在一个壶与炔属羟组和芳香的叠氮化物一起综合了。FTIR，稳固的 13C NMR 和元素的分析证实了聚合物的形成。他们俩拥有直到 410 和 900 的高 thermo 稳定性 ? 偄？？
Two rigid macrocyclic CTV-based porous organic polymers, Click-POP-1 and Click-POP-2, have been synthe- sized by Click reaction of a cyclotriveratrylene analogue with alkyne groups and aromatic azides in one pot. FTIR, solid 13C NMR and elemental analysis confirmed the formation of the polymers. Both of them possess high thermo-stability which is up to 410 and 900 ℃, respectively, and moderate hydrogen storage properties with 0.46 wt% at 77 K. Their nitrogen uptake showed type-I isotherm with BET surface areas up to 342 and 317 m2·g ^-1.
基金
the National Natural Science Foundation of China，the Major State Basic Research Development Program of China
