利用PUF被动采样技术研究长三角城市群大气中多环芳烃的时空分布及来源

PUF Passive Air Sampling of Polycyclic Aromatic Hydrocarbons in Atmosphere of the Yangtze River Delta,China:Spatio-Temporal Distribution and Potential Sources

大气是环境污染研究领域重要的介质之一,大气被动采样技术在近10年来已发展成为主动大流量采样的重要补充手段.利用聚氨酯泡沫(polyurethane foam,PUF)被动采样技术在区域尺度上对长三角城市群大气中的多环芳烃(PAHs)进行监测.通过对31组采样点的研究发现,长三角城市群大气中PAHs的浓度在10.1～367 ng.m-3之间,苯并[a]芘(BaP)年平均浓度高达2.25 ng.m-3,超出GB 3095-2012规定限值两倍多.PAHs季节变化趋势为秋季>冬季>春季>夏季,秋冬季节长三角城市群大气中BaP的超标范围较大,其中冬季有明显的BaP排放.交通石油源、煤和生物质燃烧和焦炉排放源是该区域大气中PAHs的主要来源,贡献率依次为38.1%、42.4%和19.5%.

Atmosphere is regarded to be an important media in the environmental pollution research area.Passive air sampling was one of the effective complementary sampling techniques for the active high volume air sampler in recent decades.A regional scale investigation on the atmospheric polycyclic aromatic hydrocarbons（PAHs） was conducted in the Yangtze River Delta（YRD）.Polyurethane foam based passive air samplers were used to collect the atmospheric PAHs from 31 sampling sites in this area.PAHs concentrations ranged from 10.1 ng.m-3 to 367 ng.m-3 in this study.The annual average concentration of benzo[a]pyrene（BaP） reached 2.25 ng.m-3,which was two times higher exceeding the national standard,GB 3095-2012.The atmospheric PAHs during four seasons decreased in the following order： autumn winter spring summer.Larger BaP excessive areas were found in autumn and winter than other seasons.Moreover,an obvious emission of BaP was confirmed during the winter time.Traffic related petroleum combustion,coal and biomass burning,and coke oven were identified as potential sources of atmospheric PAHs,contributing 38.1%,42.4%,and 19.5%,respectively.