水中硫酸根及溶解氧质量浓度变化对管垢金属元素释放的影响

Effect of the Change in Sulphate and Dissolved Oxygen Mass Concentration on Metal Release in Old Cast Iron Distribution Pipes

针对出厂水水质化学组分变化可能引起管垢成分释放进而导致管网"黄水"的问题,利用管段反应器,研究了硫酸根(SO24-)质量浓度变化对长期通地下水的铸铁管段总铁释放的影响,同时分析了硫酸根质量浓度变化可能造成的金属元素锰(Mn)、砷(As)、铬(Cr)、铜(Cu)、锌(Zn)和镍(Ni)的释放行为.研究表明,实验管段进水中SO24-质量浓度的升高能导致管垢总铁、Mn释放量显著增加,且当SO24->400 mg.L-1时,出水呈现明显的"黄水"现象.对实验管段进出水中微量金属元素的检测发现,尽管随着进水SO24-质量浓度的升高,出水中As、Cr、Cu、Zn和Ni质量浓度也随之增加,但其多数情况下低于进水质量浓度,说明管垢对这些微量元素具有吸附作用.增加水中溶解氧(DO)质量浓度对铁的释放具有明显控制作用,但当超过一定值时,其抑制作用反而降低.

To understand the processes of corrosion by-product release and the consequent ＂red water＂problems caused by the variation of water chemical composition in drinking water distribution system,the effect of sulphate and dissolved oxygen（DO） concentration on total iron release in corroded old iron pipe sections historically transporting groundwater was investigated in laboratory using small-scale pipe section reactors.The release behaviors of some low-level metals,such as Mn,As,Cr,Cu,Zn and Ni,in the process of iron release were also monitored.The results showed that the total iron and Mn release increased significantly with the increase of sulphate concentration,and apparent red water occurred when sulphate concentration was above 400 mg.L-1.With the increase of sulfate concentration,the effluent concentrations of As,Cr,Cu,Zn and Ni also increased obviously,however,the effluent concentrations of these metals were lower than the influent concentrations under most circumstances,which indicated that adsorption of these metals by pipe corrosion scales occurred.Increasing DO within a certain range could significantly inhibit the iron release.