期刊文献+

聚乙烯基咪唑对2,6-二甲基苯酚氧化聚合中底物的浓缩效应

Concentration Effect of Poly(N-Vinylimidazole) on Substrate during the Oxidative Polymerization of 2,6-Dimethylphenyl
下载PDF
导出
摘要 制备了铜-聚乙烯基咪唑(Cu(Ⅱ)-PVI)络合物,用于催化水介质中2,6-二甲基苯酚(DMP)的氧化聚合,与传统催化剂Cu(Ⅱ)-EDTA络合物相比,其催化效率约提高十倍。为探究Cu(Ⅱ)-PVI络合物催化效率提高的原因,采用N,N’-亚甲撑-二(丙烯酰胺)作为交联剂与N-乙烯基咪唑共聚合制备了PVI水凝胶。采用紫外可见吸收光谱研究了PVI水凝胶对DMP的吸附量随时间的变化,发现水溶液中DMP的浓度先随时间延长而降低,而PVI水凝胶中DMP的浓度则随时间延长而增加,最后达到平衡,说明PVI对反应底物DMP有浓缩效应。认为Cu(Ⅱ)-PVI络合物催化水介质中DMP氧化聚合反应时,其催化效率的提高归结为PVI微团对催化剂和反应底物的浓缩效应。 Cu(Ⅱ)-Poly(N-vinylimidazole) complex(Cu(Ⅱ)-PVI) was synthesized and employed to catalyze the oxidative polymerization of 2,6-dimethylphenyl(DMP) in water.Compared with the conventional Cu(Ⅱ)-EDTA catalyst,the Cu(Ⅱ)-PVI complex catalyst shows an enhancement in the catalytic efficiency,which is nearly ten times higher than that of Cu(Ⅱ)-EDTA complex.In order to elucidate the reason of the high catalytic efficiency of Cu(Ⅱ)-PVI complex,N,N’-methylenebisacrylamide was used as a crosslinking agent and PVI hydrogel was prepared by radical copolymerization of N-vinylimidazole and N,N’-methylenebisacrylamide.UV-vis spectrophotometer was used to monitor the change of the adsorption of DMP in PVI hydrogel with time.It was found that DMP concentration in water firstly decreases with the increase of time,while DMP concentration in PVI hydrogel increases with time and finally maintains an equilibrium,which confirms the concentration effect of PVI for DMP.The high catalytic efficiency of Cu(Ⅱ)-PVI complex can be ascribed to the concentration effect of PVI for both substrate and catalyst during the oxidative polymerization of DMP in water.
出处 《高校化学工程学报》 EI CAS CSCD 北大核心 2013年第4期610-614,共5页 Journal of Chemical Engineering of Chinese Universities
基金 国家自然科学基金资助项目(20974100) 浙江省自然科学基金资助项目(Y404299)
关键词 聚乙烯基咪唑 2 6-二甲基苯酚 氧化聚合 催化剂 浓缩效应 poly(N-vinylimidazole) 2 6-dimethylphenyl oxidative polymerization catalyst concentration effect
  • 引文网络
  • 相关文献

参考文献1

二级参考文献8

  • 1Desimonse J M. Practical approaches to green solvents [J]. Science, 2002, 297(5582): 799-803.
  • 2Saito K, Masuyama T, Oyaizu K et al. Oxidative polymerization of 2,6-dimethylphenol to form poly(2,6-dimethyl-1,4- phenyleneoxide) in water [J]. Angew Chem Int Ed, 2004, 43(6): 730-733.
  • 3SONG Shi-mo(宋世谟),WANG Zheng-lie(王正烈),ZHOU Ya-ping(周亚平).Physical Chemistry(物理化学)(4^th edition)[M].Bejiing(北京):Higher Education Press(高等教育出版社),2001.218-224.
  • 4Chung Y M, Ahn W S, Lim P K. Organic/aqueous interfacial synthesis of poly(2,6-dimethyl- 1,4-phenylene oxide) using surface-active copper complex catalysts [J]. Appl Catal A: General, 2000, 192(2): 165-174.
  • 5Tsuchida E, Nishide H, Nishiyama T. Kinetic discussion on the catalysis of copper-partially- quatemized poly(vinypyridine) complex [J]. J Polym Sei: Symposium, 1974, 47(1): 35-46.
  • 6Tsuchida E, Nishide H, Nishiyama T. Spectroscopic study on the elementary reactions of oxidative polymerization [J]. J Polym Sci: Symposium, 1974, 47(1): 47-54.
  • 7Zhong Y, Abrams C F, Lim P K. Biphasic synthesis of poly(2,6-dimethyl-1,4-phenylene oxide) using a surface-active coupling catalyst, 2: Process improvements, additional kinetic results, and proposed reaction mechanism [J]. Ind Eng Chem Res, 1995, 34(5): 1529-1535.
  • 8刘群,申屠宝卿,翁志学.少量甲苯存在下2,6-二甲基苯酚在水介质中的氧化聚合[J].高校化学工程学报,2008,22(5):906-910. 被引量:2
;
使用帮助 返回顶部