316L不锈钢钝化膜在Cl^-介质中的耐蚀机制

CORROSION BEHAVIOR IN 3.5% NaCl SOLUTION OF 316L SS PASSINATED IN AN OXIDIZING ACID LIQUOR

研究了 316L不锈钢在以硝酸为主体的氧化性介质中经过化学钝化处理形成的钝化膜在 3.5 %NaCl溶液中的电化学行为 ,运用X射线光电子能谱 (XPS)分析了钝化膜的组成与结构 ,运用交流阻抗技术研究了钝化膜的电性能 .结果表明 ,经过化学钝化处理后的成膜试样在Cl-介质中耐点蚀性能明显提高 ;钝化膜的主要组成元素Cr、Fe、Ni在膜中分别以Cr2 O3 、FeO、NiO存在 ;钝化膜呈p型半导体特性 .

The electrochemical behavior of passive film formedon on 316L stainless steel in an oxidizing acid solution was studied in the 3.5% NaCl solution. The compositions and structures of passive film were studied by X ray Photoelectron Spectroscope (XPS) and the electronic property was studied by AC impedance technology. The results indicated that the pitting resistance of passive film in 3.5% NaCl solution was greatly improved.The pitting potential was increased from 229 mV before passive treatment to 931 mV after passive treatment. The main composed elements in the passive film were existed in Cr 2O 3, FeO and NiO, and Cr was existed in hydroxide too. The Mott Schottky curve of passive film in 1 mol/L NaCl solution indicated that the passive film was p semiconductor.The relations between th compositions and structures of passive film and pitting resistance,and between the electronic property of passive film and pitting resistance were disclosed in this work.