期刊文献+

广东鹤山地区夏季大气中PAN污染特征 被引量:15

Properties of Atmospheric PAN Pollution in Heshan During Summer Time
下载PDF
导出
摘要 2012年8月6日—19日,广东大气超级监测站对广东鹤山地区大气中过氧乙酰基硝酸酯(以下简称:PAN)进行了观测,并对影响其值变化的因素进行了分析。结果表明,PAN的最高值达到了4.654×10-9,存在一定程度的光化学污染现象。PAN日变化呈典型单峰型,最高值通常出现在14:00-16:00,这与O3的日变化规律基本一致。此外,PAN值的变化与NO和NO2存在一定的相关性,PAN峰值均出现在NO与NO2比值较低的时段。 Atmospheric PAN was measured by online instrument at Guangdong Atmospheric Supersite of China, located in Heshan, in August 2012. The variation pattern and its influence factors were analyzed. During this measurement, the highest concentration of PAN was 4. 654 x 10^ -9, indicating a moderate photochemical pollution in this area. The diurnal variation of PAN showed a typical unimodal pattern with a peak at 14:00-16:00, which is similar to that of 03. Besides, PAN was also related to NO and NO2 , with peaks appeared during time with low values of φ( NO)/φ( NO2 ) ratio.
出处 《环境监测管理与技术》 2013年第4期24-27,共4页 The Administration and Technique of Environmental Monitoring
关键词 过氧乙酰基硝酸酯 污染特征 夏季 鹤山地区 PAN Pollution characteristics Summer time Heshan
  • 相关文献

参考文献7

  • 1TAYLOR 0 C. Importance of peroxyactetyl nitrate (PAN) as a phytotoxic air pollutant[J]. Air Pollute Control Assoc, 1969,19 (5) :347 -351.
  • 2BRIDIER I, CARALP F, LORIAT H, et al. Kinetic and theo- retical studies of the reactions CH3C(O) 02 + NO2 + M = CH3C (O) O2NO2 + M between 248 and 393K and between 30 and 760 Torr[J]. Phys. Chem., 1991, 95(9):3594-3600.
  • 3SINGH H B, HERLTH D, HARA D O, et al. Relationship of peroxyacetyl nitrate to active and total odd nitrogen at northern high latitude: Influence of reservior species on NOx and 03 [ J]. Geopheys Res. , 1992, 97 (D15) : 16523 - 16530.
  • 4王斌,张剑波.夏季北京市大气中PAN与PPN的监测分析[J].环境科学,2007,28(7):1621-1626. 被引量:17
  • 5杨光,张剑波,王斌.2006年夏季北京大气中PAN与PPN浓度变化和相关性分析[J].北京大学学报(自然科学版),2009,45(1):144-150. 被引量:13
  • 6张剑波,徐振强,杨光,等.一种过氧乙酰基硝酸酯浓度在线监测系统:中国,200910083332.X[P].2009-10-21.
  • 7韩志伟,张美根,胡非.生态NMHC对臭氧和PAN影响的数值模拟研究[J].环境科学学报,2002,22(3):273-278. 被引量:16

二级参考文献34

  • 1张剑波,唐孝炎.大气中PAN的测定及其与前体物的关系[J].环境化学,1994,13(1):30-39. 被引量:13
  • 2贾龙,葛茂发,徐永福,杜林,庄国顺,王殿勋.大气臭氧化学研究进展[J].化学进展,2006,18(11):1565-1574. 被引量:43
  • 3王斌,张剑波.夏季北京市大气中PAN与PPN的监测分析[J].环境科学,2007,28(7):1621-1626. 被引量:17
  • 4韩志伟.东亚地区对流层臭氧的数值模拟研究[M].北京:中国科学院大气物理研究所,2000.32-43.
  • 5白郁华 周秀骥 等.中国地区植物排放的非甲烷总烃天然源研究.中国地区大气臭氧变化及其对气候环境的影响(一)[M].北京:气象出版社,1995.120-127.
  • 6Stephens E R. The formation, reactions and properties of peroxyacyl nitrates (PANs) in photochemical air pollution. Adv Environ Sci Technol, 1969, 1(2): 119-146
  • 7Bridier I, Caralp F, Loirat H, et al. Kinetic and theoretical studies of the reactions CH3C(O)O2 + NO2 + M = CH3C (O)O2NO2 + M between 248 and 393 K and between 30 and 760 Torr. J Phys Chem, 1991, 95(9) : 3594-3600
  • 8Singh H B, Herlth D, Hara D O, et al. Relationship of peroxyacetyl nitrate to active and total odd nitrogen at northern high latitudes: Influence of reservoir species on NOx and O3 . J Geopheys Res, 1992, 97 (D15) : 16523- 16530
  • 9Rappengluck B, Melas D, Fabian P. Evidence of the impact of urban plumes on remote sites in the Eastern Mediterranean. Atmospheric Environment, 2003, 37 ( 13 ) : 1853-1864
  • 10Bottenheim J W, Sirios A, Brice K A, et al. Five years of continuous observations of PAN and ozone at a rural location in eastern Canada. J Geopheys Res, 1994, 99(D3): 5333-5352

共引文献35

同被引文献126

引证文献15

二级引证文献135

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部