含硫醌型平面杂环化合物的合成研究

Synthesis of heterocyclic compounds that contain naphthoquinone chromopphore and sulphur atoms have pianar structure

研究了 2 ,3—二氯 1 ,4—苯醌和二硫代草酰胺的反应 ,合成了三个具有平面型结构的含硫萘醌杂环化合物 ,该类杂环化合物可以作为分子内电荷转移复合物的给体或是其它有机电导和有机光导材料的合成原料 .所合成的化合物 ,经过熔点测定 ,元素分析和红外光谱分析确证了它们的结构 .此外 ,本文还探讨了该类化合物的合成机理和影响合成反应的条件 .

The reacion of 2,3dichloro1,4naphthoquinone with Dithiooxamide be dicussed in this article .And three heterocyclic compounds that contain naphthoquinone chromophore and sulphur atoms have planar structure be synthesized,they act as donating molecules for intermolecular charge transfer complexes or other organic electronic conductors (OECS) and organic photeconductors(OPCS).All synthetic compounds were characterized by their M.P,IR and elemental analysis.In addition the reaction conditions and mechanism of the reaction were discussed too.