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Microstructure and storage properties of low V-containing Ti–Cr–V hydrogen storage alloys prepared by arc melting and suction casting 被引量：5

Microstructure and storage properties of low V-containing Ti–Cr–V hydrogen storage alloys prepared by arc melting and suction casting
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摘要 The microstructure and hydrogen storage properties of low V content （Ti0.46Cr0.54）100-xVx （x = 2.5-7.1, at%） and （TiyCr1-y）95V5 （y= 0.38-0.54） alloys were investigated. These alloys were prepared by arc melting and copper mould suction casting. The structures of as-cast （Ti0.46Cr0.54）100-xVx （x = 2.5, 5.0, and 7.1） alloy ingots evolve with V contents from pure Laves-（x = 2.5） to dual-phase TiCr2-BCC structures （5.0 and 7.1）, whereas the suction-cast （Ti0.46Cr0.54）100-xVx （x =2.5, 5.0, and 7.1） alloys only contain single BCC phase. The suction-cast alloy rod （Ti0.46Cr0.54）95V5, containing only 5.0 at% V is shown to possess the optimum hydrogen absorption capacity, with the maximum hydrogen content of 3.14 wt%. Furthermore, the hydrogen storage properties of the suction-cast low V alloys （TiyCr1-y）95V5 （y = 0.38-0.54） are sensitive to Ti/Cr ratios and only those alloys with Ti/Cr ratios close to the CN14 cluster [TiTCrs] have good hydrogen storage properties. The microstructure and hydrogen storage properties of low V content （Ti0.46Cr0.54）100-xVx （x = 2.5-7.1, at%） and （TiyCr1-y）95V5 （y= 0.38-0.54） alloys were investigated. These alloys were prepared by arc melting and copper mould suction casting. The structures of as-cast （Ti0.46Cr0.54）100-xVx （x = 2.5, 5.0, and 7.1） alloy ingots evolve with V contents from pure Laves-（x = 2.5） to dual-phase TiCr2-BCC structures （5.0 and 7.1）, whereas the suction-cast （Ti0.46Cr0.54）100-xVx （x =2.5, 5.0, and 7.1） alloys only contain single BCC phase. The suction-cast alloy rod （Ti0.46Cr0.54）95V5, containing only 5.0 at% V is shown to possess the optimum hydrogen absorption capacity, with the maximum hydrogen content of 3.14 wt%. Furthermore, the hydrogen storage properties of the suction-cast low V alloys （TiyCr1-y）95V5 （y = 0.38-0.54） are sensitive to Ti/Cr ratios and only those alloys with Ti/Cr ratios close to the CN14 cluster [TiTCrs] have good hydrogen storage properties.
作者 Hai-Bin Wang Qing Wang Chuang Dong Fen Xu Li-Xian Sun Chong-Lin Chen
机构地区 Key Laboratory of Materials Modification Materials and Thermochemistry Laboratory Department of Physics and Astronomy
出处 《Rare Metals》 SCIE EI CAS CSCD 2013年第4期354-358,共5页 稀有金属（英文版）
基金 financially supported by the National Natural Science Foundation of China(Nos.51171035 and 11174044)
关键词 Ti-Cr-V alloys CLUSTER Hydrogen storageproperties Copper mould suction casting Ti-Cr-V alloys Cluster Hydrogen storageproperties Copper mould suction casting
分类号 TG139.7 [一般工业技术—材料科学与工程] TF741.5 [冶金工程—钢铁冶金]
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参考文献17

  • 1Tamura T, Kazumi T, Kamegawa A, Takamura H, Okada M. Protium absorption properties and protide formations of Ti2r- V alloys. J Alloy Compd. 2003;356-357(9):505.
  • 2Miraglia S, Rango PD, Rivoirard S, Fruchart D, Charbonnier J, Skryabina N. Hydrogen sorption properties of compounds based on BCC Til_xWl_yCrl+x+y alloys. J Alloy Compd. 2012; 536(27): 1.
  • 3Massicot B, Latroche M, Joubert JM. Hydrogenation properties of Fe-Ti-V BCC alloys. J Alloy Compd. 2011 ;509(2):372.
  • 4Nakamura Y, Nakamura J, Sakaki K, Asano K, Akiba E. Hydrogenation properties of Ti-V-Mn alloys with a BCC structure containing high and low oxygen concentrations. J Alloy Compd. 2011;509(5):1841.
  • 5Tamura T, Tominaga Y, Matsumoto K, Fuda T, Kuriiwa T, Kamegawa A, Takamura H, Okada M. Protium absorption properties of Ti-V-Cr-Mn alloys with a BCC structure. J Alloy Compd. 2002;330-332(1):522.
  • 6Yu XB, Yang ZX, Feng SL, Wu Z, Xu NX. Influence of Fe addition on hydrogen storage characteristics of Ti-V-based alloy. Int J Hydrogen Energy. 2006;31 (10): 1176.
  • 7Zheng FP, Chen LX, Wang YR, Wang XH, Li L, Chen CP. The phase structure and hydrogen storage properties of (Tio.iVo.9)l_x Fex (x = 0-0.06) alloys. J Funct Mater. 2006;37(9):1438.
  • 8Okada M, Kuriiwa ;I', Tamura T, Takamura H, Kamegawa A. Ti-V-Cr BCC alloys with high protium content. J Alloy Compd. 2002;330-332(1 ):511.
  • 9Li F, Zhao J J, Tian DX, Zhang HL, Ke XZ, Johansson B. Hydrogen storage behavior in C15 Laves phase compound TiCr2 by first principles. J Appl Phys. 2009;105(4):043707.
  • 10Zang liB, VCang Q, Dong C, Yuan L, )u F, Sun LX. Com- position design for Laves phase-related body-centered cubic-V solid solution alloys with large hydrogen storage capacities. J Phys: Condens Matter. 2008;20(1 I):114110.

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Rare Metals
2013年 第4期

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