摘要
The glass transition behavior of La55A125-Ni10CU10 bulk metallic glass was investigated using elec-trical resistivity and differential-scanning calorimetry measurements. There are good agreements of the onset temperature （Tg-onset） and the end temperature （Tg-end） of the glass transition between the DSC curve and tempera-ture dependent electrical resistivity （TER） curve in the same heating rate. Kinetics of the glass transition is studied with the electrical resistivity data. The apparent activation energy of the glass transition （△Eg） is found to be 306.4 kJ.mol^-1. Fragility parameter D^＊ and VFT temper-ature To are 9.8 and 324.9 K, respectively.
The glass transition behavior of La55A125-Ni10CU10 bulk metallic glass was investigated using elec-trical resistivity and differential-scanning calorimetry measurements. There are good agreements of the onset temperature （Tg-onset） and the end temperature （Tg-end） of the glass transition between the DSC curve and tempera-ture dependent electrical resistivity （TER） curve in the same heating rate. Kinetics of the glass transition is studied with the electrical resistivity data. The apparent activation energy of the glass transition （△Eg） is found to be 306.4 kJ.mol^-1. Fragility parameter D^＊ and VFT temper-ature To are 9.8 and 324.9 K, respectively.
基金
financially supported by the Fundamental Research Funds for the Central Universities(No.FRFTP-09-026B)
the Program for Changjiang Scholars and Innovative Research Team in University,the Specialized Research Fund for the Doctoral Program of Higher Education(No.20100006110013)
the National Natural Science Foundation of China(No.51010001)
