摘要
硅材料具有良好的力学稳定性和热稳定性,作为表面分子印迹聚合物的载体具有较大的优势。以硅材料为载体的表面分子印迹聚合物(SSMIP)是目前分子印迹技术领域的研究重点之一。着重对最近几年SSMIP的制备方法进行总结与评述,主要包括接枝共聚法、活性可控自由基聚合法、牺牲硅胶骨架法和溶胶-凝胶法等,并对SSMIP的应用和未来发展进行了展望。
Silica material is showing significant advantages in design of surface molecularly imprinted polymer due to its high mechanical and thermal stability. Silicon surface molecularly imprinted polymer （SSMIP） is one of the most active topics in the field of molecular imprinting technique. The latest achievements in the preparation of SSMIP, including grafting copolymerization process, controlled/living radical polymerization, sacrificial template method, and sol-gel process, are reviewed and discussed. The application and the prospect of SSMIP are also proposed.
出处
《材料导报》
EI
CAS
CSCD
北大核心
2013年第19期55-59,共5页
Materials Reports
基金
贵州省科学技术基金(J20112078)
贵州省教育厅自然科学基金(2010054)
贵州省特色重点学科基金(2012442)
关键词
硅材料
表面分子印迹
聚合物
接枝共聚
活性可控自由基聚合
牺牲硅胶骨架
溶胶-凝胶
silica material, surface molecular imprinting, radical polymerization, sacrificial template, sol-gel polymer, grafting copolymerization, controlled/living
