有机化合物的构性相关分析Ⅲ.卤代烃的构性相关分析

The interrelation analysis between stracture-property of organic compounds Ⅲ.The interrelation analysis between structure-property of alkyl halides

简明地描述了极性共价键概念 ,并用成键原子的电负性差说明了卤代烃分子中的 C— X(X为 F,Cl,Br,I)键都是极性共价键。同时 ,在有机化学构性相关理论指导下 ,对卤代烃进行了较系统的构性相关分析 ,揭示了它们构性之间的因果关系规律 ,并将其化学性质归纳成 3大类 :官能团的反应 ,烃基的反应 ,官能团和烃基共同参与的反应。

Polarized covalent bonds is described briefly.And it is explained that \{C—X\} bonds in alkyl halides are polarized covalent bonds with the electronegativity difference between atom-formed bonds.The interrelation analysis between structure-property of alkyl halides is done systematically by means of the interrelation theory between structure-property of organic compounds.The law of causality between structure-property of alkyl halides is brought to light.And chemical reactions of alkyl halides are divided into 3 kinds:functional group reactions,hydrocarbon radical reactions and reactions of functional group and hydrocarbon radical together.