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碳纳米管改性的蜡基复合粘结剂 被引量:1

Mixed Wax-based Binders Modified by Carbon Nanotubes
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摘要 通过熔融共混将功能化的碳纳米管引入到蜡基粘结剂中,得到碳纳米管改性的复合粘结剂.扫描电镜(SEM)显微照片显示,功能化的碳纳米管能均匀分散在粘结剂基体中.偏光显微照片和热性能分析结果表明,碳纳米管的加入能有效地提高粘结剂的结晶度和热稳定性,进而改善生坯在脱脂时的保形性.碳纳米管与粘结剂的非共价键结合有助于碳纳米管的均匀分散,更可能有利于复合材料成型后的脱脂. Carbon nanotubes (CNTs) functionalized with various surface functional groups were introduced into the fabrication of binder for metal injection moulding. Scanning Electron Microscopy (SEM) micrographs indicated that the functionalized carbon nanotubes were homogeneously dispersed in binder matrix. The polarized optical micro- scopic photographs and thermal analysis results have shown that the addition of CNTs can not only effectively improve the crystallinity and thermal stability of the binder, but may also increase the green strength of injection sample. The non-covalent bond between carbon nanotubes and polyethylene contributed to the uniform dispersion of the carbon nanotubes and the debinder of the composite.
出处 《湖南大学学报(自然科学版)》 EI CAS CSCD 北大核心 2013年第9期74-78,共5页 Journal of Hunan University:Natural Sciences
基金 国家自然科学基金资助项目(51272073 51154001)
关键词 碳纳米管 蜡基复合粘结剂 金属粉末注射成形 carbon nanotubes wax-based composite binders powder injection molding
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参考文献14

  • 1YANG J,SCHALLER R.Mechanical spectroscopy of Mg reinforced with Al2O3 short fibers and C nanotubes[J].Materials Science and Engineering A,2004,370(1/2):512-515.
  • 2孟飞,裴燕斌,果世驹.轧制对纳米碳管弥散强化铜基复合材料微观组织的影响[J].粉末冶金材料科学与工程,2005,10(1):55-59. 被引量:10
  • 3WALID M D,BYUNG K L,CHAN B M.Electrical and mechanical properties of carbon nanotube reinforced copper nanocomposites fabricated by electroless deposition proces[J].Materials Science and Engineering A,2009,513/514:247-253.
  • 4CHA S I,KIM T K,ARSHAD S N,et al.Extraordinary strengthening effect of carbon nanotubes in metal-matrix nanocomposites processed by molecular-level mixing[J].Adv Mater,2005,17:1377-1381.
  • 5XU L S,CHEN X H,PAN W Y.Thermal expansion of MW CNT-reinforced copper composite[J].Transactions of Nonferrous Metals Society of China,2007,17:S1065-S1069.
  • 6MOBALLEGH L,MORSHEDIAN J,ESFANDEH M.Copper injection molding using a thermoplastic binder based on paraffin wax[J].Materials Letters,2005,59(22):2832-2837.
  • 7SIDAMBEA A T,FIGUEROA I A,HAMILTON H G C,et al.Metal injection moulding of CP-Ti components for biomedical applications[J].Journal of Materials Processing Technology,2012,212(7):1591-1597.
  • 8HUANG M S,HSU H C.Effect of backbone polymer on properties of 316L stainless steel MIM compact[J].Journal of Materials Processing Technology,2009,209(15/16):5527-5535.
  • 9THOMAS VIELMA P,CERVERAA,LEVENFELDB,et al.Production of alumina parts by powder injection molding with a binder system based on high density polyethylene[J].Journal of the European Ceramic Society,2008,28(4):763-771.
  • 10TAO T,ZHANG L,MA J,et al.The production of flexible and electrically conductive polyethylene carbon nanotube shish-kebab structures and their assembly into thin fllms[J].Industrial & Engineering Chemistry Research,2012,51(15):5456-5460.

二级参考文献10

  • 1[1]Groza J R, Gibeling J C. Principles of particle selection for dispersion-strengthened copper [J]. Materials Science and Engineering A, 1993, A171(1 - 2): 115 -125.
  • 2[2]Stephan R. Carbon naotube: exceptional mechanical and electrical properties [J]. Annales de Chimie Science des Materiaux, 2000, 25(7): 529-532.
  • 3[3]Kuzumaki T, Miyazawa K. Processing of carbon nanotube reinforced aluminum composite [J]. Journal of Materials Research, 1998, 13(10): 2445 - 2449.
  • 4[4]Lau K T, Hui D. Effectiveness of using carbon nanotubes as nano-reinforcements for advanced composite structure [J]. Carbon, 2002, 40(9): 1597 - 1617.
  • 5[5]Peigney A, Laurent C H, Flahaut E. Carbon nanotubes in novel ceramic matrix nanocomposites [J]. Ceramics International, 2000, 26(6): 677 - 683.
  • 6[6]Deshmukh A R, Sundararajan T. Analysis of cold densification rolling of a sintered porous metal strip[J]. Journal of Materials Processing Technology,1998, 84(1-3): 56-72.
  • 7[8]Srivatsan T S, Narendra N, Troxell J D. Tensile deformation and fracture behavior of an oxide dispersion strengthened copper alloy [J]. Materials and Design,2000, 21(3): 191-198.
  • 8[9]Lu L, Sui M L, Lu K. Ultrahigh strength and high electrical conductivity in copper [J]. Science, 2000, 287(25) : 1463 - 1467.
  • 9[10]Yutaka S S, Mitsunori U. Hall-petch relationship in friction stir welds of equal channel angular-pressed aluminum alloys [J]. Materials Science and Engineering A, 2003, A354(1-2): 298-305.
  • 10[12]Naser J, Ferkel H. Grain stabilization of copper with nanoscaled Al2 O3-powder [J]. Materials Science and Engineering A, 1997, A234 - 236(2): 470 - 473.

共引文献9

同被引文献11

  • 1李文华,陈小华,张刚,陈传盛,胡静,许龙山,杨植.溶液法制备聚丙烯/碳纳米管复合材料的结晶行为[J].高分子材料科学与工程,2007,23(2):194-197. 被引量:9
  • 2ZOFIA M,WLADYSLAW K. Separation of Cr(VI) on ehitosanmembranes[J]. Ind Eng Chem Res Mark, 1999, 38: 4946--4950.
  • 3BAEK S H,KIM B, SUH K D. Chitosan particle/multiwall carbon nanotube composites by electrostatic interactions[J]. Colloids and Surfaces A:Physicochem Eng Aspects, 2008,316: 292--296.
  • 4WANG S F, SHEN L, ZHANG W D, et al. Preparation and mechanical properties of chitosan/carbon nanotubes compos- ites[J]. Biomacromolecules, 2005,6 (6) : 3067 -- 3072.
  • 5HU Y, CHEN W, LU L H,et al. Electromechanical actuation with controllable motion based on a single-walled carbon nano- tube and natural biopolymer composite[J]. ACS NANO, 2010, 6(4) :3498--3502.
  • 6QIU S,WU L G, PAN X J,et al. Preparation and properties of functionalized carbon nanotube/PSF blend ultrafiltration membranes[J]. Journal of Membrane Science, 2009,342:165 --172.
  • 7TANG C Y,ZHANG Q,WANG K,etal. Water transport be- havior of ehitosan porous membranes containing multi--walled carbon nanotubes (MWNTs)[J]. Journal of Membrane Sci enee, 2009,37 : 240-- 247.
  • 8马如飞,李铁虎,庄强,赵廷凯.静电自组装碳纳米管/壳聚糖复合材料[J].炭素技术,2009,28(2):9-12. 被引量:8
  • 9卢月美,巩前明,梁吉.碳纳米管/活性炭复合微球的制备及其对VB_(12)的吸附应用[J].物理化学学报,2009,25(8):1697-1702. 被引量:8
  • 10刘强,孟范平,姚瑞华,张爱静.添加剂聚乙二醇对壳聚糖超滤膜结构和性能的影响[J].膜科学与技术,2010,30(1):24-29. 被引量:12

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