期刊文献+

核壳结构ACR乳液的合成及粒径的控制 被引量:1

Synthesis of Core-shell Structure Acrylic Latex and Control of Particle Size
下载PDF
导出
摘要 采用乳液聚合合成了以聚丙烯酸丁酯/聚苯乙烯(PBA/PS)为核,PBA为中间层及聚甲基丙烯酸甲酯(PMMA)为壳的胶乳。重点研究了聚合条件对丙烯酸酯类聚合物(ACR)各层粒径特别是核层乳液粒径及性能的影响。粒度分析表明:通过改变聚合工艺可以得到粒径不同的ACR胶乳,且具有明显的核壳结构。 Acrylic latex with PBA/PS as the core, PBA as the inter layer and the PMMA as the outer layer was synthesized by emulsion polymerization. The effect of polymerization conditions on the particle size and emulsion property was studied. It was found that latex with different particle size was obtained by changing polymerization conditions, and the latex particles exhibited obvious core-shell structure.
出处 《塑料工业》 CAS CSCD 北大核心 2013年第10期89-92,共4页 China Plastics Industry
关键词 种子乳液聚合 粒径 核壳结构 Seed Emulsion Polymerization Particle Size Core-shell Structure
  • 相关文献

参考文献7

  • 1GAILLARD C, FUCHS G, PLUMMER C, et al. The mor- phology of sub-mieronsized core-shell latex particles: An e- lectron microscopy study [ J ]. Micron, 2007, 38 (5) : 522 - 535.
  • 2YU H B, PENG J, ZHAI M L, et al. Synthesis and char-acterization of poly ( n-butyl acrylate) -poly ( methyl meth- acrylate) latex interpenetrating polymer networks by radiation induced seeded emulsion polymerization [ J ]. Radiat Phys Chem, 2007, 76 (11-12): 1746-1750.
  • 3包永忠,翁志学,黄志明.ACR抗冲改性剂合成、结构及其对应用性能的影响[J].塑料助剂,2003(2):18-23. 被引量:4
  • 4CHO K, YANG J H, YOON S, et al. Toughening of poly- carbonate : Effect of particle size and rubber phase contents of the core-shell impact modifier [ J ]. J Appl Polym Sci, 2005, 95 (3): 748-755.
  • 5杨敏,潘明旺,万林战,张留成.共聚型丙烯酸酯抗冲改性剂的合成及其对PVC的改性[J].塑料工业,2002,30(4):46-48. 被引量:7
  • 6ZHOU C, LIU H, CHEN M, et al. Toughening of polyvi- nyl-chloride by methyl methacrylate-but-adiene-styrene core shell rubber particles : Influence of rubber particle size [ J ]. Polym Eng Sci, 2012, 52 (12) : 2523 -2529.
  • 7HASSAN A, HAWORTH B. Impact properties of acrylate rubber-modified PVC : Influence of temperature [ J ]. J Ma- ter Process Technol, 2006, 172 (3) : 341 -345.

二级参考文献9

  • 1温绍国.ACR-g-VC合成技术原理与性能[D].杭州:浙江大学,1999.
  • 2Chok M A, Yang J. Park CE. [J]. Polymer, 1998,39(14) :3073.
  • 3Winnik M A, Zhao C L.[J] .Langmuir, 1993(9):2053.
  • 4Sommer F, Duc T M, et al. [J] . Langmuir, 1995(11) :440.
  • 5Landfester K. Boeffel C, et al. [J]. Macromol, 1996(29) :5972.
  • 6Ishida M, Oshima J, et al. [J]. Polymer, 1999(40) : 3323.
  • 7Song J Y, Kim J W, Sub K D. [ J ]. J. Applied.Polym. Sci., 1999(71) :1607.
  • 8洪涛.ACR在PVC塑料加工中的应用[J].塑料科技,1990,18(3):20-23. 被引量:1
  • 9于元章,卢晓,魏文杰,吕秀玲.抗冲型ACR树脂的改性效果及应用[J].塑料工业,2000,28(5):25-27. 被引量:3

共引文献9

同被引文献5

引证文献1

二级引证文献7

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部