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Fabrication of Fe_2O_3@polypyrrole Nanotubes and the Catalytic Properties Under the Ultrasound 被引量:5

Fabrication of Fe_2O_3@polypyrrole Nanotubes and the Catalytic Properties Under the Ultrasound
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摘要 Fe2O3@polypyrrole nanotubes (Fe2O3@PPy nanotubes) have been successfully prepared by in-situ polymerization of the pyrrole on the surface of Fe2O3 nanotubes (Fe2O3-NTs), via using L-Lysine as modified surfactant. Hollow PPy nanotubes were also produced by dissolution of the Fe2O3 core from the core/shell composite nanotubes with 1 mol,L-1 HC1. Scanning electron microscopy(SEM), transmission electron microscope (TEM), selective-area electron diffraction (SAED), X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy(FT-IR) confirmed the formation of Fe2O3-NTs and Fe2O3@PPy core/shell nanotubes. Its catalytic properties were investigated under the ultrasound. The results of UV-vis spectroscopy (UV) demonstrated Rhodamine B (RhB) can be efficiently degraded by Fe2O3 @PPy nanotubes. Fe2O3@polypyrrole nanotubes (Fe2O3@PPy nanotubes) have been successfully prepared by in-situ polymerization of the pyrrole on the surface of Fe2O3 nanotubes (Fe2O3-NTs), via using L-Lysine as modified surfactant. Hollow PPy nanotubes were also produced by dissolution of the Fe2O3 core from the core/shell composite nanotubes with 1 mol,L-1 HC1. Scanning electron microscopy(SEM), transmission electron microscope (TEM), selective-area electron diffraction (SAED), X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy(FT-IR) confirmed the formation of Fe2O3-NTs and Fe2O3@PPy core/shell nanotubes. Its catalytic properties were investigated under the ultrasound. The results of UV-vis spectroscopy (UV) demonstrated Rhodamine B (RhB) can be efficiently degraded by Fe2O3 @PPy nanotubes.
出处 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2013年第5期990-996,共7页 武汉理工大学学报(材料科学英文版)
关键词 Fe2O3 nanotubes composites POLYPYRROLE POLYMERISATION CATALYSIS rhodamine B Fe2O3 nanotubes composites polypyrrole polymerisation catalysis rhodamine B
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