摘要
We described the preparation of copper oxide composite nanofibers doped with carbon nanotubes （CuO/C-NFs） or nickel oxide（CuO/NiO-NFs） by electrospinning for direct glucose determination. The interest in exploring practical CuO/C-NFs and CuO/NiO-NFs electrode materials for sensor application was fascinated by the possibility of promoting electron transfer for kinetically unfavorable glucose oxidation reactions at a lower overpo- tential and thus improving the selectivity of the electrode for glucose in electroanalysis. The morphologies of CuO/C-NFs and CuO/NiO-NFs were characterized by scanning electron microscopy（SEM） and X-ray powder diffraction（XRD）. The electrocatalytic performances of glucose were evaluated in detail by cyclic voltammetry（CV） and chronoamperometry. Facile charge transport, enhanced current response（at a lower overpotential of ＋0.35 V）, improved stability and selectivity, as well as excellent resistance towards electrode fouling were observed at CuO/ C-NFs electrode in direct glucose electroanalysis. These merits are attributed to the highly porous three-dimensional network film structure of CuO/C-NFs electrode materials and the potential synergic catalytic effect of CuO and carbon nanotubes in composite nanofibers. This study may provide a new insight into metal oxide-based composite nanofibers obtained via electrospinning for fabricating novel and high performance sensors and devices.
We described the preparation of copper oxide composite nanofibers doped with carbon nanotubes （CuO/C-NFs） or nickel oxide（CuO/NiO-NFs） by electrospinning for direct glucose determination. The interest in exploring practical CuO/C-NFs and CuO/NiO-NFs electrode materials for sensor application was fascinated by the possibility of promoting electron transfer for kinetically unfavorable glucose oxidation reactions at a lower overpo- tential and thus improving the selectivity of the electrode for glucose in electroanalysis. The morphologies of CuO/C-NFs and CuO/NiO-NFs were characterized by scanning electron microscopy（SEM） and X-ray powder diffraction（XRD）. The electrocatalytic performances of glucose were evaluated in detail by cyclic voltammetry（CV） and chronoamperometry. Facile charge transport, enhanced current response（at a lower overpotential of ＋0.35 V）, improved stability and selectivity, as well as excellent resistance towards electrode fouling were observed at CuO/ C-NFs electrode in direct glucose electroanalysis. These merits are attributed to the highly porous three-dimensional network film structure of CuO/C-NFs electrode materials and the potential synergic catalytic effect of CuO and carbon nanotubes in composite nanofibers. This study may provide a new insight into metal oxide-based composite nanofibers obtained via electrospinning for fabricating novel and high performance sensors and devices.
基金
Supported by the National Natural Science Foundation of China（Nos. 21075048, 20543003）.
