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锂离子电池电极材料SEI膜的研究概况 被引量:4

Research survey on SEI film for electrode material of lithium ion batteries
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摘要 综述了锂离子电池电极材料表面的"固体电解质界面膜"(SEI膜)的成膜机理及研究概况,并分析了电解液、温度和电流密度对SEI膜形成过程的影响;在此基础上,对SEI膜的改性(主要包括电极材料的改性和添加电解液添加剂)进行了分析,认为SEI膜的研究将对电极材料和电解液添加剂的改进研究产生重要影响。 The research survey and formation principle of solid electrolyte interface (SEI) fihn applied on the surface of elec- trode material of lithium ion batteries were summarized.The effects of electrolyte, temperature, and current density on the es- tablishment process of SEI film were analyzed.On the basis of that the modification (mainly including the modification of electrode material and adding electrolyte additive) of SEI were also discussed.It's believed that the research of SEI film will have an important influence on the improvement research of electrode materials and electrolyte additive.
出处 《无机盐工业》 CAS 北大核心 2013年第10期56-59,共4页 Inorganic Chemicals Industry
基金 天津市自然科学基金资助项目(11JCYBJC08000)
关键词 锂离子电池 电极材料 SEI膜 lithium ion batteries electrode material SEI film
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参考文献23

  • 1Aurbach D, Zinigrad E, Yaron C, et al.A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions [J].Solid State Ionics,2002,148 (3/4):405- 416.
  • 2徐仲榆,郑洪河.锂离子蓄电池碳负极/电解液相容性研究进展Ⅰ碳电极界面化学与碳负极/电解液的相容性[J].电源技术,2000,24(3):171-177. 被引量:36
  • 3Yang C R, Song J Y, Wang Y Y, et aI.Impedance spectroscopic study for the initiation of passive film on carbon electrodes in lithi- um ion batteries [ J ].J.Applied Electrochemistry, 2000,30 ( 1 ) : 29- 34.
  • 4Schlaikjer C R.The kinetics of the reduction of thionyl chloride [J ]. J.Power Sources, 1989,26 ( 1/2 ) : 161-177.
  • 5Ostrovskii D, Ronci F, Scrosati B, et al.A FTIR and Raman study of spontaneous reactions occurring at the LiNiyCo(1-y)O2 electrode/non- aqueous electrolyte interface[J].J.Power Sources,2001,94 (2): 183-188.
  • 6Striebel K A, Sakai E, Cairns E J.Impedance sttldies of the thin film LiMn2O4/electrolyte interface [J ].Electrochem.Soe., 2002,149 ( 1 ) : 61-68.
  • 7Peled E ,Tow D B ,Merson A ,et al.Composition,depth profiles and lateral distribution of materials in the SEI built on HOPG-TOF SIMS and XPS studies [J ].J.Power Sources, 2001,97/98 : 52-57.
  • 8Yang C R, Wang Y Y, Wan C C. Composition analysis of the pas- sive film on the carbon electrode of a lithium-ion battery with an EC-based electrolyte [ J ] .J.Power Sources, 1998,72 ( 1 ) : 66-70.
  • 9郑明森,马军,董全峰,林祖赓.正极材料表面的SEI膜形成及锂离子扩散动力学[J].电池,2007,37(3):199-200. 被引量:4
  • 10Pyun S, Kim K H, Han J N.Analysis of stresses generated during hydrogen extraction from and injection into Ni (OH)2/NiOOH film electrode [J ].J.Power Sources, 2000,91 (2) : 92-98.

二级参考文献23

  • 1高菲,戴永年,姚耀春.锂离子电池非水电解液添加剂的研究进展[J].电池工业,2005,10(5):309-313. 被引量:4
  • 2马树华,国汉举,李季,梁洪泽,景遐斌,王佛松.锂离子电池负极碳材料的表面改性与修饰Ⅰ.表面的氧化、还原处理对碳材料电极性能的影响[J].电化学,1996,2(4):413-419. 被引量:17
  • 3Moumouzias G,Ritzoulis G, Siapkas D, et al. Comparative study of LiBF4, LiAsF6, LiPF6, and LiCIO4 as electrolytes in propylene carbonate-diethyl carbonate solutions for Li/LiMn2O4 cells[J]. Power sources, 2003, 122(1) :57--66.
  • 4Yamamoto H, Saisho K. Non-aqueous electrolye seondary battery: US , US 2007/0072074 A1 [P]. 2006-9--27.
  • 5Hitoshi O, Kunihisa S, Makoto U,et al. Effect of vinylene carbonate as additive to electrolyte for lithium metal anode[J]. ElectrochimicaActa, 2004,49 (4): 565 --572.
  • 6Edstrom K, Andersson A M, Bishop A, et al. Carbon electrode morphology and thermal stability of the passiration layer[J]. Power Sources, 2001,97-98 z 87- 91.
  • 7MacNeil D D. Comparison of the reactivity of various carbon electrode with electrolyte at elevated temperature[J]. Electrochem Soc, 1999,146(10):3 596-- 3 602.
  • 8Hung F Y, Lui T S, Liao H C.A study of nano-sized surface coating on LiMn204 materials[J]. Applied Surface Sciencce, 2007,253 (18) :7443-7448.
  • 9Lee Y S, Kumada N,Yoshio M.Synthesis and characterization of lithium aluminum-doped spinel (LiPrxMn2 O4) for lithium secon- dary battery [J ] .J.Power Source, 2001,96 ( 2 ) : 376-384.
  • 10Aurbach D, Markovsky B, Levi M D, et al. New insights into the interaction between electrode materials and electrolyte solutions for advanced nonaqueous batteries[ J ]. J Power Sources, 1999,81-82 : 95-111.

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