摘要
以2-萘胺为原料,经重氮化反应、还原反应制得2-萘肼,再与甲基异丙基酮经费歇尔吲哚合成反应制得2,3,3-三甲基-1H-苯并[e]吲哚,再经烷基化反应制得几种不同取代基的苯并吲哚衍生物,其结构经1HNMR表征,并初步研究了几种衍生物的光谱性质.
By using 2-naphthylamine as raw material, 2-naphthalene hydrazine was synthesized through diazotization and reduction reaction. Then 2, 3, 3-trimethyl-benzo [e] indole was obtained when the 2-naphthalene hydrazine reacted with methyl isopropyl ketone. Several benzindole derivatives with different substituent groups were obtained through alkylation reaction. The structures were characterized by IHNMR and a preliminary study of the spectral quality of the derivatives was conducted.
出处
《天津城市建设学院学报》
CAS
2013年第3期208-210,共3页
Journal of Tianjin Institute of Urban Construction
基金
国家自然科学基金(51178289)
天津市高等学校科技发展基金计划项目(20110509)
关键词
2-萘胺
苯并吲哚
荧光光谱
2-naphthylamine
benzindole
fluorescence spectra