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Orthorhombic 3-LiV2O5 as Cathode Materials in Lithium Ion Batteries: Synthesis and Property

Orthorhombic 3-LiV2O5 as Cathode Materials in Lithium Ion Batteries: Synthesis and Property
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摘要 The rod-like and bundle-like v-LiV205 were synthesized via a simple solvothermal process- ing. The rod-like 7-LiV205 with diameter of 500-800 nm and the bundle-like architectures are composed of several of order-attached rods with diameter of 100-600 nm. "y-LiV205 were synthesized using LiOH.H20, NH4VO3, HNO3, C2H5OH without and with PVP as raw materials. At the same time, the actual formation mechanism of Y-LiV205 was also investigated. As the cathode materials for lithium ion batteries, the bundle-like Y-LiV205 prepared with PVP delivers a better electrochemical performance, which has an initial dis charge capacity of 269.3 mAh/g at a current density of 30 mA/g and is still able to achieve 228 mAh/g after the 20th cycle. The good electrochemical properties of the as-synthesized Y-LiV205 coupled with the simple, relatively low temperature, and low cost of the prepara tion method may make this material a promising candidate as a cathode material for lithium ion batteries.
出处 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2013年第5期597-600,I0004,共5页 化学物理学报(英文)
关键词 Lithium ion battery Electrochemical property Cathode material 7-LiV2O5 锂离子电池 电化学性能 正极材料 合成 斜方晶系 C2H5OH 氢氧化锂 电流密度
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