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Study of K/Mn-MgO Supported Fe Catalysts with Fe(CO)5 and Fe(NO3)3 as Precursors for CO Hydrogenation to Light Alkenes 被引量:3

Study of K/Mn-MgO Supported Fe Catalysts with Fe(CO)5 and Fe(NO3)3 as Precursors for CO Hydrogenation to Light Alkenes
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摘要 Two K/Mn-MgO supported catalysts were prepared by Fe(CO)5 and Fe(NO3)3 as precursor respectively. The obtained Fe-K/Mn-MgO catalysts were tested for CO hydrogenation to light alkenes and characterized by X-ray powder diffraction (XRD), X-ray photoelectron spectra (XPS), H2 temperature-programmed reduction (H2-TPR), H2 CO and CO2 temperature-programmed desorption (H2, CO/CO2-TPD) and transmission electron microscope (TEM) The results indicated that the catalyst with 10 wt% Fe loading prepared by Fe(CO)5 as precursor showed better performance in syngas to light alkenes than ones obtained from Fe(NO3)3 as precursor, where the CO conversion was 62.50% and the selectivity was 55.95% at 350 ℃, 1.5 MPa and 1000 h^-1, respectively. Two K/Mn-MgO supported catalysts were prepared by Fe(CO)5 and Fe(NO3)3 as precursor respectively. The obtained Fe-K/Mn-MgO catalysts were tested for CO hydrogenation to light alkenes and characterized by X-ray powder diffraction (XRD), X-ray photoelectron spectra (XPS), H2 temperature-programmed reduction (H2-TPR), H2 CO and CO2 temperature-programmed desorption (H2, CO/CO2-TPD) and transmission electron microscope (TEM) The results indicated that the catalyst with 10 wt% Fe loading prepared by Fe(CO)5 as precursor showed better performance in syngas to light alkenes than ones obtained from Fe(NO3)3 as precursor, where the CO conversion was 62.50% and the selectivity was 55.95% at 350 ℃, 1.5 MPa and 1000 h^-1, respectively.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2013年第10期1263-1268,共6页 中国化学(英文版)
关键词 iron precursor light alkenes CO conversion SELECTIVITY iron precursor, light alkenes, CO conversion, selectivity
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同被引文献41

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