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溶胶—凝胶法合成棒状β-Mn_2V_2O_7锂电池负极材料

Preparation of Rodlike β-Mn_2V_2O-7 for Lithium Battery Anode Materials by Sol-Gel Method
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摘要 采用溶胶—凝胶法成功制备了棒状β-Mn2V2O7锂电池负极材料。结果表明,合成的β-Mn2V2O7的纯度高、形貌规整有序,首次放电比容量达590mAh/g,40圈内容量较第二圈基本没有衰减。 Rodlike β-Mn2V2O7 with high purity and good uniformity for lithium battery anode materials was prepared by sol-gel method.The results show that the initial specific capacity of β-Mn2V2O7 is 590 mAh/g and β-Mn2V2O7 has good stability after 40 circulations without any loss of capacity.
出处 《有色金属(冶炼部分)》 CAS 北大核心 2013年第10期60-63,共4页 Nonferrous Metals(Extractive Metallurgy)
基金 湖北省自然科学基金项目(2012FFB04906) 武汉科技大学基金项目(2011xz012)
关键词 锂离子电池 负极材料 β-Mn2V2O7 溶胶凝胶法 lithium iron battery anode material β-Mn2V2O7 sol-gel method
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参考文献13

  • 1黄可龙,王兆翔,刘素琴.锂离子电池原理与关键技术[M].北京:化学工业出版社,2007:12.
  • 2刘奕,钱逸泰.MnV_2O_6纳米片的简易水热合成[J].无机材料学报,2007,22(6):1139-1141. 被引量:1
  • 3Piffard Y, Leroux F, Guyomard Det, et al. The amor phous oxides MnV2 O6+δ (0<δ<1) as high capacity neg ative electrode materials for lithium batteries[J]. Jour nal of Power Sources, 1997,68(2) :698-703.
  • 4Liao J H, Leroux, F, Payen C, et al. Synthesis, struc tures, magnetic properties, and phase transition of man- ganese(II) divanadate: Mn2V207 [J]. Journal of Solid State Chemistry, 1996,121 : 214-224.
  • 5Ponomarenko L A, Vasil'ev A N. Magnetic properties of Cu2V2O7[J]. Physica B,2000,284-288(2): 1459- 1460.
  • 6Kataev V, Pommer J, Choi K Y, et al. Mangnetic ex- change in a low-dimensional complex oxide (Cu, Zn) 2 V2 07 [J]. Journal of Magnetism and Magnetic Ma- terials, 2004,272-276 : 933-934.
  • 7Touaiher M, Rissouli K, Benkhouja K, et al. Crystal structures and magnetic properties of M2 V2 07 (M= Co, Ni and Cu) compounds[J].Materials Chemistry and Physics Phys. ,2004,85(1) :41-46.
  • 8Buckley A M,Bramwell S T,Day P,et al. The magnetic properties and structures of the transition metal py- roarsenates M2As207 (M= Ni, Co, Mn) [J]. Journal of Solid State Chemistry,1995,115(1) :229-235.
  • 9He Z Z, Yutaka U. Magnetic properties of Mn2V2O7 single crystals [J]. Journal of Solid State Chemistry, 2008,181(2) :235-238.
  • 10Liu Y, Zeng Yu-Ping. Controllable synthesis of beta- Mn2V207 microtubes and hollow microspheres [J].Materials Letters, 2009,63 : 28-30.

二级参考文献17

  • 1张建荣,高濂.水热法合成纳米SnO_2粉体[J].无机材料学报,2004,19(5):1177-1180. 被引量:17
  • 2施尔畏,夏长泰,王步国,仲维卓.水热法的应用与发展[J].无机材料学报,1996,11(2):193-206. 被引量:287
  • 3Wang Z L,Pan Z W.Adv.Mater.,2002,14 (15):1029-1032.
  • 4Huang M H,Maom S,Feick H,et al.Science,2001,292(5523):1897-1899.
  • 5Chung S W,Yu J Y,Heath J R.Appl.Phys.Lett.,2000,76 (15):2068-2070.
  • 6Cui Y,Wei Q Q,Park H,et al.Science,2001,293(5533):1289-1292.
  • 7Tans S J,Devoret M H,Dal H,et al.Nature,1997,386(6624):474-477.
  • 8Wang Z L.Adv.Mater.,2000,12 (17):1295-1298.
  • 9Piffard Y,Leroux F,Guyomard D,et al.J.Power Sources,1997,68 (2):698-703.
  • 10Leroux F,Piffard Y,Ourvard G,et al.Chem.Mater.,1999,11 (10):2948-2959.

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