摘要
通过置换反应,在锌基底上制得银纳米涂层,经十二烷基硫醇(DDT)、十八烷基硫醇(ODT)表面修饰后表现出较好的超疏水性和抗腐蚀性,接触角达到151.8°和156.2°,滚动角接近5°.涂层表面的超疏水性受反应时间、AgNO3浓度及化学表面能的控制.本文对银纳米涂层超疏水效应的形成及其抗腐蚀性进行了分析、探讨.
Silver nano coatings were fabricated on zinc substrate by a facile method of replacement reaction. The coatings enhibit properties of superhydrophobicity and anticorrosion after being modified by dodecanethiol (DDT) and octadecanethiol (ODT). Contact angles on modified coating are 156.2° and 151.8°, respectively, and the glide angle is approximately 5°. Silver coatings' superhydrophobicity is dominated by reaction time, concentration of AgNO3 and surface free energy. Finally, superhydrophobic and anticorrosion mechanisms of the coatings were analyzed and discussed.
出处
《科学通报》
EI
CAS
CSCD
北大核心
2013年第28期2934-2939,共6页
Chinese Science Bulletin
基金
国家自然科学基金(20873101)
甘肃省高校河西走廊特色资源利用省级重点实验室面上项目(ZX1101)资助
关键词
银纳米涂层
超疏水性
抗腐蚀性
阶层结构
表面修饰
silver nano-coating, superhydrophobicity, anti-corrosion quality, hierarchical structure, surface modification