硫代-Iniferters法活性自由基嵌段共聚合

Living Free-radical Block Copolymerization Using Thio-iniferters

自由基活性聚合近年来发展很快 ,本文在概述了自由基活性聚合及其最新进展的基础上 ,对硫代 - Iniferters法自由基活性聚合的机理、硫代 -

On the basis of concerning with living radical polymerization and its latest development,This article reviewed the mechanism of free radical living polymerization with thio\|iniferters,systhesis of macroinitiators using thio\|iniferters and their applications in preparement of block copolymers,such as PMA\|PS\|PMMA\,PMMA\|PS\,PMMA\|PS\|PMMA\,PVAc\|PS\|PVAc and multiblock copolymers etc.