摘要
报道了两个 [V2 M6S6O2 ](M =Cu ,Ag)八核簇合物的合成和分子结构 ,讨论它们的红外光谱 ,51VNMR和电子光谱 ,采用动态红外光谱跟踪技术探讨 [V2 Cu6S6O2 ]簇合物的成簇机理。
The syntheses and molecular structures of two octa nuclear [V 2M 6S 6O 2](M=Cu,Ag) clusters derived from [VS 4] 3- have been reported in this paper.Their infrared, 51 V NMR and electronic spectra have also been assigned and discussed.The formation mechanism of octa nuclear [V 2Cu 6S 6O 2] cluster has been explored by means of active IR capture technique.
出处
《光谱学与光谱分析》
SCIE
EI
CAS
CSCD
北大核心
2000年第6期785-787,共3页
Spectroscopy and Spectral Analysis
基金
国家和福建省自然科学基金资助
关键词
V-Cu(Ag)-S簇合物
分子结构
光谱表征
成族机理
V—Cu(Ag)—S clusters, Molecular structure, Spectroscopic characterization, Formation mechanism