乙炔二价阴离子的配位化学和Raman光谱

Coordination Chemistry and Raman Spectra of Acetylide Dianion

报道了乙炔银与可溶性银盐形成复盐的合成过程 ,研究了C2 -2 在复盐里的配位方式和C2 -2 的Ra man光谱 ,讨论了C2 -2 阴离子的配位化学与等电体N2

This paper shows the syntheses of double salts of silver acetylide with various soluble silver salts,investigations on the coordination modes of acetylide dianion and their Raman spectra,discussion of the relationship between the coordination chemistry of acetylide dianion and the bind mode of N 2 molecule in the FeMoco factor of nitrogenase.The results present that the bind mode of N 2 molecule inside the FeMoco factor of nitrogenase is more reasonable.